Enantioselective intramolecular [2+2+2] cycloaddition of triynes for the synthesis of atropisomeric chiral ortho-diarylbenzene derivatives

Takanori Shibata, Kyoji Tsuchikama, Maiko Otsuka

研究成果: Article

57 引用 (Scopus)

抜粋

An iridium-chiral diphosphine complex was used to catalyze an enantioselective [2+2+2] cycloaddition of oxygen- and nitrogen-bridged triynes with ortho-substituted aryl groups on their termini. ortho-Diarylbenzenes with atropisomeric chiralities were obtained in high yield and enantiomeric excess.

元の言語English
ページ(範囲)614-619
ページ数6
ジャーナルTetrahedron Asymmetry
17
発行部数4
DOI
出版物ステータスPublished - 2006 2 20

ASJC Scopus subject areas

  • Catalysis
  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Inorganic Chemistry

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