Enantioselective synthesis of planar-chiral benzosiloloferrocenes by Rh-catalyzed intramolecular C-H silylation

Takanori Shibata, Tsubasa Shizuno, Tomoya Sasaki

    研究成果: Article査読

    65 被引用数 (Scopus)

    抄録

    The first synthesis of planar-chiral benzosiloloferrocenes was achieved by the intramolecular reaction of 2-(dimethylhydrosilyl)arylferrocenes. The enantioselective cross dehydrogenative coupling of an sp<sup>2</sup> C-H bond of ferrocene with a Si-H bond proceeded efficiently with the use of a Rh-chiral diene catalyst.

    本文言語English
    ページ(範囲)7802-7804
    ページ数3
    ジャーナルChemical Communications
    51
    37
    DOI
    出版ステータスPublished - 2015 5 7

    ASJC Scopus subject areas

    • Chemistry(all)
    • Catalysis
    • Ceramics and Composites
    • Electronic, Optical and Magnetic Materials
    • Surfaces, Coatings and Films
    • Materials Chemistry
    • Metals and Alloys

    フィンガープリント 「Enantioselective synthesis of planar-chiral benzosiloloferrocenes by Rh-catalyzed intramolecular C-H silylation」の研究トピックを掘り下げます。これらがまとまってユニークなフィンガープリントを構成します。

    引用スタイル