抄録
Layered silica/surfactant mesostructured thin films containing chlorophyllous pigments [C13 2-demethoxycarbonyl-pheophytin b (pyroPheo b) or zinc C 13 2-demethoxycarbonyl-chlorophyll b (Zn-pyroChl b)] have been prepared on an indium tin oxide (ITO) electrode grafted with a chlorophyll derivative possessing a triethoxysilyl group (copper C13 2-demethoxycarbonyl-chlorophyllide a 3-triethoxysilyl propylamide, Cu-APTES-Chl a) to achieve effective light harvesting and successive photocurrent generation by the mesostructured films. The incorporation of pyroPheo b and Zn-pyroChl b in the mesostructured film resulted in 1.2- and 1.6-fold increases of the photocurrent density, respectively, as compared to the case of an antenna pigment-free film also grafted to a surface-modified ITO electrode. The difference action spectra, between the electrodes with and without the antenna pigments, coincided well with the absorption spectra of the immobilized pigments. Because direct electron injection from the antenna pigments in the mesostructured films to the ITO electrode was scarcely observed, the energy transfer from the antenna pigments to Cu-APTES-Chla plays an important role for the increase in photocurrent density. The usefulness of the mesostructured films as model systems is discussed in relation to the photosynthetic primary processes of higher plants.
| 元の言語 | English |
|---|---|
| ページ（範囲） | 3992-3997 |
| ページ数 | 6 |
| ジャーナル | Langmuir |
| 巻 | 21 |
| 発行部数 | 9 |
| DOI | |
| 出版物ステータス | Published - 2005 4 26 |
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ASJC Scopus subject areas
- Physical and Theoretical Chemistry
- Colloid and Surface Chemistry
これを引用
Energy transfer between chlorophyll derivatives in silica mesostructured films and photocurrent generation. / Furukawa, Hiroyasu; Inoue, Natsuka; Watanabe, Tadashi; Kuroda, Kazuyuki.
：: Langmuir, 巻 21, 番号 9, 26.04.2005, p. 3992-3997.研究成果: Article
}
TY - JOUR
T1 - Energy transfer between chlorophyll derivatives in silica mesostructured films and photocurrent generation
AU - Furukawa, Hiroyasu
AU - Inoue, Natsuka
AU - Watanabe, Tadashi
AU - Kuroda, Kazuyuki
PY - 2005/4/26
Y1 - 2005/4/26
N2 - Layered silica/surfactant mesostructured thin films containing chlorophyllous pigments [C13 2-demethoxycarbonyl-pheophytin b (pyroPheo b) or zinc C 13 2-demethoxycarbonyl-chlorophyll b (Zn-pyroChl b)] have been prepared on an indium tin oxide (ITO) electrode grafted with a chlorophyll derivative possessing a triethoxysilyl group (copper C13 2-demethoxycarbonyl-chlorophyllide a 3-triethoxysilyl propylamide, Cu-APTES-Chl a) to achieve effective light harvesting and successive photocurrent generation by the mesostructured films. The incorporation of pyroPheo b and Zn-pyroChl b in the mesostructured film resulted in 1.2- and 1.6-fold increases of the photocurrent density, respectively, as compared to the case of an antenna pigment-free film also grafted to a surface-modified ITO electrode. The difference action spectra, between the electrodes with and without the antenna pigments, coincided well with the absorption spectra of the immobilized pigments. Because direct electron injection from the antenna pigments in the mesostructured films to the ITO electrode was scarcely observed, the energy transfer from the antenna pigments to Cu-APTES-Chla plays an important role for the increase in photocurrent density. The usefulness of the mesostructured films as model systems is discussed in relation to the photosynthetic primary processes of higher plants.
AB - Layered silica/surfactant mesostructured thin films containing chlorophyllous pigments [C13 2-demethoxycarbonyl-pheophytin b (pyroPheo b) or zinc C 13 2-demethoxycarbonyl-chlorophyll b (Zn-pyroChl b)] have been prepared on an indium tin oxide (ITO) electrode grafted with a chlorophyll derivative possessing a triethoxysilyl group (copper C13 2-demethoxycarbonyl-chlorophyllide a 3-triethoxysilyl propylamide, Cu-APTES-Chl a) to achieve effective light harvesting and successive photocurrent generation by the mesostructured films. The incorporation of pyroPheo b and Zn-pyroChl b in the mesostructured film resulted in 1.2- and 1.6-fold increases of the photocurrent density, respectively, as compared to the case of an antenna pigment-free film also grafted to a surface-modified ITO electrode. The difference action spectra, between the electrodes with and without the antenna pigments, coincided well with the absorption spectra of the immobilized pigments. Because direct electron injection from the antenna pigments in the mesostructured films to the ITO electrode was scarcely observed, the energy transfer from the antenna pigments to Cu-APTES-Chla plays an important role for the increase in photocurrent density. The usefulness of the mesostructured films as model systems is discussed in relation to the photosynthetic primary processes of higher plants.
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U2 - 10.1021/la047845z
DO - 10.1021/la047845z
M3 - Article
C2 - 15835966
AN - SCOPUS:18544375170
VL - 21
SP - 3992
EP - 3997
JO - Langmuir
JF - Langmuir
SN - 0743-7463
IS - 9
ER -