Enhancement of the high-rate capability of solid-state lithium batteries by nanoscale interfacial modification

Narumi Ohta, Kazunori Takada, Lianqi Zhang, Renzhi Ma, Minoru Osada, Takayoshi Sasaki

研究成果: Article

391 引用 (Scopus)

抄録

The enhancement of the high-rate capability of solid-state Lithium Batteries by nanoscale interfacial modification, was analyzed. The surface of LiCoO2 with Li4Ti5O12 was coated by spray coating. When the sulfide electrolytes were in contact with the oxide electrodes, the large difference between their chemical potentials make their Li+ ions transfer from the sulfide electrolytes to the oxide electrodes. Electrochemical impedance spectroscopy demonstrated the reduction of the interfacial resistance by the interposition of Li4Ti 5O12. Developed space-charge layer on the sulfide side and very large interfacial resistance improved the high-rate capability of solid-state lithium batteries. This enhancement of capability supports the practical application of solid-state lithium batteries and, hence provides a solution to the safety concerns of lithium batteries.

元の言語English
ページ(範囲)2226-2229
ページ数4
ジャーナルAdvanced Materials
18
発行部数17
DOI
出版物ステータスPublished - 2006 9 5
外部発表Yes

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Lithium batteries
Sulfides
Oxides
Electrolytes
Electrodes
Chemical potential
Electrochemical impedance spectroscopy
Electric space charge
Ions
Coatings

ASJC Scopus subject areas

  • Materials Science(all)

これを引用

Enhancement of the high-rate capability of solid-state lithium batteries by nanoscale interfacial modification. / Ohta, Narumi; Takada, Kazunori; Zhang, Lianqi; Ma, Renzhi; Osada, Minoru; Sasaki, Takayoshi.

:: Advanced Materials, 巻 18, 番号 17, 05.09.2006, p. 2226-2229.

研究成果: Article

Ohta, Narumi ; Takada, Kazunori ; Zhang, Lianqi ; Ma, Renzhi ; Osada, Minoru ; Sasaki, Takayoshi. / Enhancement of the high-rate capability of solid-state lithium batteries by nanoscale interfacial modification. :: Advanced Materials. 2006 ; 巻 18, 番号 17. pp. 2226-2229.
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