抄録
Premixed stoichiometric flames of acetylene, ethylene, and ethane with air were studied using a chemical scheme composed of 82 pairs of elementary reactions to demonstrate the dependence of the propagation mechanisms of C2 hydrocarbon flames on the heat release distribution. The general role of heat release distribution through flames was depicted through an analytical treatment of the governing equations with the thermal properties of the gases being constant and the temperature profile given by an appropriate function of the flame position. The results showed that the amount of heat released by chemical reactions at low-temperature regions of a flame is of fundamental importance for its propagation and that the main trigger of exothermic reactions at those zone is hydrogen atoms, which diffuses from the flame front. In the acetylene flame reactions, consuming hydrogen atoms at the low-temperature region yielded all the heat released at this zone. Heat release distribution extended down to low-temperature regions led to large burning velocities although the amount of heat released at each position was small.
| 元の言語 | English |
|---|---|
| ページ（範囲） | 3098-3104 |
| ページ数 | 7 |
| ジャーナル | Bulletin of the Chemical Society of Japan |
| 巻 | 64 |
| 発行部数 | 10 |
| 出版物ステータス | Published - 1991 10 1 |
| 外部発表 | Yes |
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ASJC Scopus subject areas
- Chemistry(all)
これを引用
Exothermic reactions in C2 hydrocarbon flames. / Fukutani, Seishiro; Kunioshi, Nilson; Sakagughi, Keizo; Jinno, Hiroshi.
：: Bulletin of the Chemical Society of Japan, 巻 64, 番号 10, 01.10.1991, p. 3098-3104.研究成果: Article
}
TY - JOUR
T1 - Exothermic reactions in C2 hydrocarbon flames
AU - Fukutani, Seishiro
AU - Kunioshi, Nilson
AU - Sakagughi, Keizo
AU - Jinno, Hiroshi
PY - 1991/10/1
Y1 - 1991/10/1
N2 - Premixed stoichiometric flames of acetylene, ethylene, and ethane with air were studied using a chemical scheme composed of 82 pairs of elementary reactions to demonstrate the dependence of the propagation mechanisms of C2 hydrocarbon flames on the heat release distribution. The general role of heat release distribution through flames was depicted through an analytical treatment of the governing equations with the thermal properties of the gases being constant and the temperature profile given by an appropriate function of the flame position. The results showed that the amount of heat released by chemical reactions at low-temperature regions of a flame is of fundamental importance for its propagation and that the main trigger of exothermic reactions at those zone is hydrogen atoms, which diffuses from the flame front. In the acetylene flame reactions, consuming hydrogen atoms at the low-temperature region yielded all the heat released at this zone. Heat release distribution extended down to low-temperature regions led to large burning velocities although the amount of heat released at each position was small.
AB - Premixed stoichiometric flames of acetylene, ethylene, and ethane with air were studied using a chemical scheme composed of 82 pairs of elementary reactions to demonstrate the dependence of the propagation mechanisms of C2 hydrocarbon flames on the heat release distribution. The general role of heat release distribution through flames was depicted through an analytical treatment of the governing equations with the thermal properties of the gases being constant and the temperature profile given by an appropriate function of the flame position. The results showed that the amount of heat released by chemical reactions at low-temperature regions of a flame is of fundamental importance for its propagation and that the main trigger of exothermic reactions at those zone is hydrogen atoms, which diffuses from the flame front. In the acetylene flame reactions, consuming hydrogen atoms at the low-temperature region yielded all the heat released at this zone. Heat release distribution extended down to low-temperature regions led to large burning velocities although the amount of heat released at each position was small.
UR - http://www.scopus.com/inward/record.url?scp=85039770559&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=85039770559&partnerID=8YFLogxK
M3 - Article
AN - SCOPUS:85039770559
VL - 64
SP - 3098
EP - 3104
JO - Bulletin of the Chemical Society of Japan
JF - Bulletin of the Chemical Society of Japan
SN - 0009-2673
IS - 10
ER -