Experimental determination of the dipole moment of HCl dimer using an electrostatic hexapole field

K. Imura*, T. Kasai, H. Ohoyama, H. Takahashi, R. Naaman

*この研究の対応する著者

研究成果: Article査読

16 被引用数 (Scopus)

抄録

HCl dimers were prepared in a pulsed supersonic beam of neat HCl. The dimers were focused in an electrostatic hexapole field. Using computer simulation, the focusing curve could be fit, assuming contributions from both first and second order Stark effects. The dipole moment, based on simulation, was found to be 1.5 ± 0.1 D. The ability to observe an effective dipole moment in a system where the donor-acceptor tunneling is fast is surprising. It may indicate that the understanding of the interaction of floppy systems with hexapole field is not complete.

本文言語English
ページ(範囲)356-360
ページ数5
ジャーナルChemical Physics Letters
259
3-4
DOI
出版ステータスPublished - 1996 9月 6
外部発表はい

ASJC Scopus subject areas

  • 物理学および天文学(全般)
  • 物理化学および理論化学

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