Experiments on the simultaneous partitioning of divalent metal ions between sphalerite or garnet and 2M aqueous chloride solutions under supercritical conditions

Etsuo Uchida, Michiyuki Fukuma, Fumitoshi Sato, Sho Endo

研究成果: Article査読

抄録

Experiments on the simultaneous partitioning of divalent metal ions were performed in the systems (1) ZnS (sphalerite)-(Ni2+, Co2+, Fe2+, Mn2+, Cd2+)C12-H2O and (2) Mn3Al2Si3O12 (spessartine)-(Ni2+, Mg2+, Co2+, Zn2+, Fe2+, Ca2+)C12-H2O in the temperature range of 500 to 800°C at 1 kb. In the former system for ion partitioning in the 4-fold coordination, parabola-shaped PC-IR curves with a peak near Zn2+ were obtained and no anomaly was observed for Zn2+ and Ni2+ but Cd2+. In the latter system for ion partitioning in the 8-fold coordination, parabola-shaped PC-IR curves with a peak near Mn2+ were obtained, but Zn2+ deviates from such a trend and tends to concentrate into aqueous chloride solutions. The PC-IR curves for spessartine are gentle compared with those for sphalerite. The PC-IR curves both for spessartine and sphalerite become gentle with increasing temperature.

本文言語English
ページ(範囲)151-162
ページ数12
ジャーナルJapanese Magazine of Mineralogical and Petrological Sciences
33
4
DOI
出版ステータスPublished - 2004

ASJC Scopus subject areas

  • Geochemistry and Petrology
  • Economic Geology

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