Fabrication and anisotropic electronic property for oriented Li1+xyNb1−x−3yTix+4yO3 solid solution by slip casting in a high magnetic field

Hiromi Nakano, Shohei Furuya, Motohiro Yuasa, Tohru Suzuki, Hitoshi Ohsato

研究成果: Article

4 引用 (Scopus)

抜粋

The Li1+xyNb1−x−3yTix+4yO3 (0.06 ≤ x ≤ 0.33, 0 ≤ y ≤ 0.09) (hereafter LNT), forms a unique and periodical structure in the Li2O-Nb2O5-TiO2 ternary system. In this work, toward application of the unique qualities of an electro-ceramic, we fabricated oriented LNT balk ceramics by slip casting in a strong magnetic field of 12 T using various sizes of particles. The c-axis of the LNT powders was aligned parallel to the magnetic field. As a result, we found anisotropic- and unique- electric properties which were caused by a superstructure with intergrowth layers of corundum-type [Ti2O3]2+. The Qf value parallel to the c-axis was about five times greater than that of perpendicular to the c-axis. We first clarified the mechanism showing that the anisotropic Qf value was caused by the anisotropic electron conductivity and the anisotropic bonding strength in the superstructure.

元の言語English
ページ(範囲)2373-2379
ページ数7
ジャーナルAdvanced Powder Technology
28
発行部数9
DOI
出版物ステータスPublished - 2017 9 1
外部発表Yes

ASJC Scopus subject areas

  • Chemical Engineering(all)
  • Mechanics of Materials

フィンガープリント Fabrication and anisotropic electronic property for oriented Li<sub>1+</sub><sub>x</sub><sub>−</sub><sub>y</sub>Nb<sub>1−</sub><sub>x</sub><sub>−3</sub><sub>y</sub>Ti<sub>x</sub><sub>+4</sub><sub>y</sub>O<sub>3</sub> solid solution by slip casting in a high magnetic field' の研究トピックを掘り下げます。これらはともに一意のフィンガープリントを構成します。

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