Fabrication of grain-aligned thick films of thermoelectric oxides by an electrophoretic deposition method under high magnetic fields

Taichi Okamoto, Shigeru Horii, Toshiaki Kumagai, Jun Ichi Shimoyama, Kohji Kishio, Tetsuo Uchikoshi, Tohru Suzuki, Yoshio Sakka

研究成果: Conference contribution

抄録

We report the preparation of grain-aligned [Ca2CoO 3-δ]0.62CoO2 (Ca349) thick films by a simultaneous use of electrophoretic deposition (EPD) and magneto-science methods, and multi-layered thick films composed of Ca349, and Ca 0.9La0.1MnO3-δ(Mn113) and Al 2O3 using the EPD method. The thick films with the orders from 10-6 to 10-3 m in thickness were fabricated at high deposition rates of the order of 10-5 m/min by optimization of the suspension component and the control of applied electric field for the EPD process. The EPD thick films processed through appropriate heat-treatment for densification showed almost same thermoelectric properties with their bulk samples. The Ca349 thick films deposited under high magnetic fields exhibited high degree of c-axis grain-orientation, and remarkable reduction of resistivity perpendicular to the applied magnetic field was observed. The Al 2O3/Mn113/Al2O3/Ca349/Al 2O3 multi-layered thick films have been successfully prepared by the optimization of the EPD process. Our present results indicate the effectiveness of the EPD process (under high magnetic fields) as an integration technique of thermoelectric modules for high temperature power generation.

本文言語English
ホスト出版物のタイトルElectroceramic Materials and Applications - Proceedings of the 6th Pacific Rim Conference on Ceramic and Glass Technology
ページ257-266
ページ数10
出版ステータスPublished - 2006
外部発表はい
イベント6th Pacific Rim Conference on Ceramic and Glass Technology - Maui, Hawaii, United States
継続期間: 2005 9 112005 9 16

出版物シリーズ

名前Ceramic Transactions
196
ISSN(印刷版)1042-1122

Other

Other6th Pacific Rim Conference on Ceramic and Glass Technology
国/地域United States
CityMaui, Hawaii
Period05/9/1105/9/16

ASJC Scopus subject areas

  • セラミックおよび複合材料
  • 材料化学

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