Facile Synthesis of Poly(Glycidyl Ether)s with Ionic Pendant Groups by Thiol-Ene Reactions

Kan Hatakeyama-Sato, Satoshi Kimura, Satoshi Matsumoto, Kenichi Oyaizu

研究成果: Article査読

1 被引用数 (Scopus)

抄録

Poly(glycidyl ether)s having trifluoromethanesulfonylimide or imidazolium pendant groups are synthesized by thiol-ene reactions. The precise synthesis of a precursor polymer, poly(allyl glycidyl ether), and the following click reactions enable the facile preparation of the polyelectrolytes with the controlled length of main and side chains. The low glass transition temperature (<<0 °C) of the polyethers is beneficial to provide a conductivity as high as 10−6 S cm−1 at room temperature, without compositing any additives. The synthetic approach has advantages of clearly comparing the structural effects of the introduced functional groups and facilely preparing the comprehensive types of polymers.

本文言語English
論文番号1900399
ジャーナルMacromolecular rapid communications
41
1
DOI
出版ステータスPublished - 2020 1 1

ASJC Scopus subject areas

  • Organic Chemistry
  • Polymers and Plastics
  • Materials Chemistry

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