Formation of a palladalactone complex by C-O bond cleavage of diketene promoted by a zerovalent palladium complex

Ryuki Kakino, Kazuhiro Nagayama, Yoshihito Kayaki, Isao Shimizu, Akio Yamamoto

研究成果: Article

17 引用 (Scopus)

抜粋

The reaction of diketene with [Pd(PMe3)2(styrene)] 1 at room temperature gave [Pd(OCOCH2C=CH2)(PMe,3)2] 2 through cleavage of the C-O bond adjacent to the carbon bearing the exomethylene group. The structure of 2 was fully established by spectroscopic means, elemental analysis and single-crystal X-ray analysis. The reactivity of 2 has been investigated.

元の言語English
ページ(範囲)685-686
ページ数2
ジャーナルChemistry Letters
発行部数7
出版物ステータスPublished - 1999

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ASJC Scopus subject areas

  • Chemistry(all)

これを引用

Kakino, R., Nagayama, K., Kayaki, Y., Shimizu, I., & Yamamoto, A. (1999). Formation of a palladalactone complex by C-O bond cleavage of diketene promoted by a zerovalent palladium complex. Chemistry Letters, (7), 685-686.