Formation of silicate nanoscrolls through solvothermal treatment of layered octosilicate intercalated with organoammonium ions

Yusuke Asakura, Megumi Sugihara, Takeru Hirohashi, Aya Torimoto, Takuya Matsumoto, Masakazu Koike, Yoshiyuki Kuroda, Hiroaki Wada, Atsushi Shimojima, Kazuyuki Kuroda

研究成果: Article

抄録

We report silicate nanoscrolls composed of only SiO4 tetrahedra with crystalline walls for the first time in this study. The procedure consists of the intercalation of layered octosilicate with dioctadecyldimethylammonium bromide ((C18)2DMABr) and the subsequent solvothermal treatment of the intercalated material in heptane. The walls of the obtained nanoscrolls are crystalline, which originates from layer crystallinity in the pristine silicate. The direction of rolling up is fixed at the a- or b-axis of the silicate based on the electron diffraction patterns of the nanoscrolls. Desorption of (C18)2DMABr, which is present in addition to (C18)2DMA cations, from the interlayer during solvothermal treatment is likely related to the nanoscrolling process. Although the yield of nanoscrolls is low, these findings will lead to the re-estimation of many layered silicates intercalated with long-chain alkylammonium compounds as precursors for silicate nanoscrolls with crystalline walls.

元の言語English
ページ(範囲)12924-12931
ページ数8
ジャーナルNanoscale
11
発行部数27
DOI
出版物ステータスPublished - 2019 7 21

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Silicates
Ions
Crystalline materials
Heptanes
Heptane
Intercalation
Bromides
Electron diffraction
Diffraction patterns
Cations
Desorption
Positive ions
octosilicate

ASJC Scopus subject areas

  • Materials Science(all)

これを引用

Formation of silicate nanoscrolls through solvothermal treatment of layered octosilicate intercalated with organoammonium ions. / Asakura, Yusuke; Sugihara, Megumi; Hirohashi, Takeru; Torimoto, Aya; Matsumoto, Takuya; Koike, Masakazu; Kuroda, Yoshiyuki; Wada, Hiroaki; Shimojima, Atsushi; Kuroda, Kazuyuki.

:: Nanoscale, 巻 11, 番号 27, 21.07.2019, p. 12924-12931.

研究成果: Article

Asakura Y, Sugihara M, Hirohashi T, Torimoto A, Matsumoto T, Koike M その他. Formation of silicate nanoscrolls through solvothermal treatment of layered octosilicate intercalated with organoammonium ions. Nanoscale. 2019 7 21;11(27):12924-12931. https://doi.org/10.1039/c9nr01651a
Asakura, Yusuke ; Sugihara, Megumi ; Hirohashi, Takeru ; Torimoto, Aya ; Matsumoto, Takuya ; Koike, Masakazu ; Kuroda, Yoshiyuki ; Wada, Hiroaki ; Shimojima, Atsushi ; Kuroda, Kazuyuki. / Formation of silicate nanoscrolls through solvothermal treatment of layered octosilicate intercalated with organoammonium ions. :: Nanoscale. 2019 ; 巻 11, 番号 27. pp. 12924-12931.
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