TY - JOUR
T1 - Free energy of mixing and vapour pressure of liquid Ga-As, In-As, Ga-P and In-P alloys
AU - Yamaguchi, Katsunori
AU - Itagaki, Kimio
AU - Mikula, Adolf
PY - 1998/4/1
Y1 - 1998/4/1
N2 - The change of the Gibbs energy of the reaction between group IIIA and VA elements to form a liquid III-V alloy was derived for the Ga-As, In-As, Ga-P and In-P systems by combining the heat content of the alloy with the heat and entropy of formation of the equiatomic compound at a reference temperature. The obtained data were analysed by using a Redlich-Kister polynomial equation and the optimized parameters were derived for a temperature range between 873 and 1523 K and a composition range between xv = 0 and 0.5 (for the Ga-P system between xp = 0 and 0.1). The partial pressures of these liquid alloys were expressed as a function of alloy composition and temperature. Partial pressure and total pressure-composition-temperature diagrams were constructed.
AB - The change of the Gibbs energy of the reaction between group IIIA and VA elements to form a liquid III-V alloy was derived for the Ga-As, In-As, Ga-P and In-P systems by combining the heat content of the alloy with the heat and entropy of formation of the equiatomic compound at a reference temperature. The obtained data were analysed by using a Redlich-Kister polynomial equation and the optimized parameters were derived for a temperature range between 873 and 1523 K and a composition range between xv = 0 and 0.5 (for the Ga-P system between xp = 0 and 0.1). The partial pressures of these liquid alloys were expressed as a function of alloy composition and temperature. Partial pressure and total pressure-composition-temperature diagrams were constructed.
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M3 - Article
AN - SCOPUS:0032050903
VL - 89
SP - 279
EP - 285
JO - International Journal of Materials Research
JF - International Journal of Materials Research
SN - 1862-5282
IS - 4
ER -