Free radical polymerization kinetics of vinylsulfonic acid and highly acidic properties of its polymer

Teruyuki Okayasu, Toshiyasu Hibino, Hiroyuki Nishide

研究成果: Article

9 引用 (Scopus)

抄録

Poly(vinylsulfonic acid) (PVS) possesses a high acid content (ion-exchange capacity in the chemical formula = 9.2 meq · g-1). Its monomer, vinylsulfonic acid (VSA), had a high acid dissociation ability (Hammett acid function = 0.74 in water), and a high ionic conductivity (0.04-0.11 S · cm-1). The radical polymerization of VSA with various initiators was kinetically investigated. The ESR spectrum of the VSA polymerization mixture showed a strong signal ascribed to the propagation carbon radical of VSA. The molecular weight of PVS increased with the increasing monomer concentration and decreasing radical initiator concentration to yield the PVS with a molecular weight of 4.0 × 104. Proton-conductivity of PVS under hydrated and nonhumidified conditions was on the order of 10-1 and 10-3-10-6 S · cm-1, respectively. Poly(vinylsulfonic acid) (PVS) has a high acid density (IEC=9.2 meq·g-1) and is the solid-state organic analog of sulfuric acid. Radical polymerization of the acid form of vinylsulfonic acid is kinetically investigated. PVS with a high molecular weight is obtained as a transparent membrane and shows a high proton-conductivity under both hydrated and nonhumidified conditions.

元の言語English
ページ(範囲)1072-1079
ページ数8
ジャーナルMacromolecular Chemistry and Physics
212
発行部数10
DOI
出版物ステータスPublished - 2011 5 17

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Free radical polymerization
free radicals
Polymers
polymerization
acids
Kinetics
Acids
kinetics
polymers
Proton conductivity
Molecular weight
Monomers
molecular weight
Ionic conductivity
Paramagnetic resonance
initiators
Ion exchange
Carbon
Polymerization
ethylenesulfonic acid

ASJC Scopus subject areas

  • Materials Chemistry
  • Polymers and Plastics
  • Organic Chemistry
  • Physical and Theoretical Chemistry
  • Condensed Matter Physics

これを引用

Free radical polymerization kinetics of vinylsulfonic acid and highly acidic properties of its polymer. / Okayasu, Teruyuki; Hibino, Toshiyasu; Nishide, Hiroyuki.

:: Macromolecular Chemistry and Physics, 巻 212, 番号 10, 17.05.2011, p. 1072-1079.

研究成果: Article

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KW - proton-conductivity

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KW - sulfonic acid polymer

KW - vinyl compound

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