High-pressure stopped-flow apparatus for the study of fast reactions in solution

Koji Ishihara, Shigenobu Funahashi, Motoharu Tanaka

研究成果: Article

51 引用 (Scopus)

抜粋

A high-pressure stopped-flow apparatus with spectrophotometric detection has been exploited, which enables one to follow fast reactions in various media at pressure up to 2000 kg cm-2. The rate of the following reactions was successfully measured at various pressures: (1) reaction of nickel (II) nitrate with 1-(2-pyridylazo)-2-naphthol in glacial acetic acid and (2) reaction of nickel (II) perchlorate with isoquinoline in N,N-dimethylformamide. The apparatus allows the measurement of activation volumes for reactions with half-lives longer than several milliseconds.

元の言語English
ページ(範囲)1231-1234
ページ数4
ジャーナルReview of Scientific Instruments
53
発行部数8
DOI
出版物ステータスPublished - 1982 12 1

ASJC Scopus subject areas

  • Instrumentation

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