Highly enantioselective preparation of tricyclo[4.4.0.05,7]decene derivatives via catalytic asymmetric intramolecular cyclopropanation reactions of α-diazo-β-keto esters

Ryoji Ida, Masahisa Nakada

研究成果: Article

25 引用 (Scopus)

抜粋

The enantioselective preparation of the tricyclo[4.4.0.05,7]dec-2-ene derivatives via the catalytic asymmetric intramolecular cyclopropanation (CAIMCP) reactions of α-diazo-β-keto esters with excellent ee (95-98% ee) is described. The chiral building blocks reported herein would be versatile intermediates for enantioselective natural products synthesis.

元の言語English
ページ(範囲)4855-4859
ページ数5
ジャーナルTetrahedron Letters
48
発行部数28
DOI
出版物ステータスPublished - 2007 7 9

ASJC Scopus subject areas

  • Biochemistry
  • Drug Discovery
  • Organic Chemistry

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