Hindered biaryls by C-H coupling: Bisoxazoline-Pd catalysis leading to enantioselective C-H coupling

Kazuya Yamaguchi; Junichiro Yamaguchi; Armido Studer; Kenichiro Itami

doi:10.1039/c2sc20277h

Hindered biaryls by C-H coupling: Bisoxazoline-Pd catalysis leading to enantioselective C-H coupling

Kazuya Yamaguchi, Junichiro Yamaguchi, Armido Studer, Kenichiro Itami

研究成果: Article › 査読

134 被引用数 (Scopus)

抄録

A new Pd-catalyzed C-H/C-B coupling of sterically hindered heteroarenes and arylboronic acids has been identified. The newly established Pd(OAc) ₂/bisoxazoline/TEMPO system not only enables the synthesis of sterically hindered heterobiaryls but also offers an opportunity for enantioselective biaryl coupling through C-H functionalization.

本文言語	English
ページ（範囲）	2165-2169
ページ数	5
ジャーナル	Chemical Science
巻	3
号	6
DOI	https://doi.org/10.1039/c2sc20277h
出版ステータス	Published - 2012 6 1
外部発表	はい

ASJC Scopus subject areas

Chemistry(all)

文献へのアクセス

10.1039/c2sc20277h

フィンガープリント「Hindered biaryls by C-H coupling: Bisoxazoline-Pd catalysis leading to enantioselective C-H coupling」の研究トピックを掘り下げます。これらがまとまってユニークなフィンガープリントを構成します。

引用スタイル

@article{f4e5aa098b3e475da6c7363a5a2ee0fb,

title = "Hindered biaryls by C-H coupling: Bisoxazoline-Pd catalysis leading to enantioselective C-H coupling",

abstract = "A new Pd-catalyzed C-H/C-B coupling of sterically hindered heteroarenes and arylboronic acids has been identified. The newly established Pd(OAc) 2/bisoxazoline/TEMPO system not only enables the synthesis of sterically hindered heterobiaryls but also offers an opportunity for enantioselective biaryl coupling through C-H functionalization.",

author = "Kazuya Yamaguchi and Junichiro Yamaguchi and Armido Studer and Kenichiro Itami",

year = "2012",

month = jun,

day = "1",

doi = "10.1039/c2sc20277h",

language = "English",

volume = "3",

pages = "2165--2169",

journal = "Chemical Science",

issn = "2041-6520",

publisher = "Royal Society of Chemistry",

number = "6",

}

TY - JOUR

T1 - Hindered biaryls by C-H coupling

T2 - Bisoxazoline-Pd catalysis leading to enantioselective C-H coupling

AU - Yamaguchi, Kazuya

AU - Yamaguchi, Junichiro

AU - Studer, Armido

AU - Itami, Kenichiro

PY - 2012/6/1

Y1 - 2012/6/1

N2 - A new Pd-catalyzed C-H/C-B coupling of sterically hindered heteroarenes and arylboronic acids has been identified. The newly established Pd(OAc) 2/bisoxazoline/TEMPO system not only enables the synthesis of sterically hindered heterobiaryls but also offers an opportunity for enantioselective biaryl coupling through C-H functionalization.

AB - A new Pd-catalyzed C-H/C-B coupling of sterically hindered heteroarenes and arylboronic acids has been identified. The newly established Pd(OAc) 2/bisoxazoline/TEMPO system not only enables the synthesis of sterically hindered heterobiaryls but also offers an opportunity for enantioselective biaryl coupling through C-H functionalization.

UR - http://www.scopus.com/inward/record.url?scp=84864268965&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=84864268965&partnerID=8YFLogxK

U2 - 10.1039/c2sc20277h

DO - 10.1039/c2sc20277h

M3 - Article

AN - SCOPUS:84864268965

VL - 3

SP - 2165

EP - 2169

JO - Chemical Science

JF - Chemical Science

SN - 2041-6520

IS - 6

ER -