Hydrosilylation in the 2D interlayer space between inorganic layers: Reaction between immobilized C=C groups on the interlayer surface of layered perovskite HLaNb2O7·x H2O and chlorohydrosilanes

Satoru Yoshioka, Yosuke Takeda, Yuko Uchimaru, Yoshiyuki Sugahara*

*この研究の対応する著者

研究成果査読

16 被引用数 (Scopus)

抄録

The C=C bonds immobilized in the interlayer space of layered perovskite, HLaNb2O7·xH2O, have undergone hydrosilylation reactions with chlorohydrosilanes. The C-C bonds are immobilized by the reaction between an n-propoxyl derivative of HLaNb2O7·xH2O and 4-penten-1-ol to form a CH2=CH(CH2)3 O- derivative of HLaNb2O7·xH2O, and a corresponding increase in the interlayer distance from 1.54 to 1.85 nm is observed. The CH2=CH(CH2)3 O- derivative is further treated with dichloromethylsilane or trichlorosilane, and the interlayer distance increases to 2.41 (dichloromethylsilane) or 2.07 (trichlorosilane) nm. Solid-state 13C-CP/MAS-NMR spectroscopy and infra-red (IR) spectroscopy reveal that the C-C groups disappear after the treatment with dichloromethylsilane or trichlorosilane, and 13C-NMR signals assignable to the hydrosilylated products are clearly observed. Besides hydrosilylation reactions, siloxane formation involving hydrolysis of the Si-Cl groups also proceeds. The structure of the perovskite-like slabs in HLaNb2O7·xH 2O is preserved throughout the process, indicating the successful modification of immobilized C-C groups via hydrosilylation with no structural change in the inorganic host layers.

本文言語English
ページ(範囲)145-150
ページ数6
ジャーナルJournal of Organometallic Chemistry
686
1-2
DOI
出版ステータスPublished - 2003 12 1

ASJC Scopus subject areas

  • 生化学
  • 物理化学および理論化学
  • 有機化学
  • 無機化学
  • 材料化学

フィンガープリント

「Hydrosilylation in the 2D interlayer space between inorganic layers: Reaction between immobilized C=C groups on the interlayer surface of layered perovskite HLaNb<sub>2</sub>O<sub>7</sub>·x H<sub>2</sub>O and chlorohydrosilanes」の研究トピックを掘り下げます。これらがまとまってユニークなフィンガープリントを構成します。

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