Immobilization of heme complex by radiation polymerization

Hiroyuki Nishide, M. Kato, E. Tsuchida

研究成果: Article

7 引用 (Scopus)

抜粋

Transparent films containing an iron-porphyrin complex were synthesized by 60Co γ-ray irradiation of aqueous solutions of ironporphyrin complex and a water soluble monomer such as 2-hydroxyethylmethacrylate or 1-vinyl-2-pyrrolidone. The iron(II)porphyrin complex was immobilized in the film by covalent bonding without any denaturation, under anaerobic condition or by protection of the ironporphyrin complex with carbon monoxide. After the irradiation of iron(III)porphyrin, the central iron ion was reduced spontaneously to the ferrous state. The films containing the iron(II)porphyrin adsorbed quantitatively carbon monoxide gas.

元の言語English
ページ(範囲)579-581
ページ数3
ジャーナルEuropean Polymer Journal
17
発行部数5
DOI
出版物ステータスPublished - 1981

ASJC Scopus subject areas

  • Organic Chemistry
  • Polymers and Plastics

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