抄録
Highly transparent silica-surfactant nanocomposite films containing photosynthetic pigments have been successfully formed through the solubilization of chlorophyll a (Chl a) into surfactant micelles. The UV-vis absorption spectra indicated that a large amount of Chl a were transformed into pheophytin a in the films. These photosynthetic pigments were well dispersed in the surfactant assemblies and their chlorin rings were exposed to the surface of silica layers. Even under an air atmosphere, the photostability of immobilized pigments was largely improved in comparison with that in a homogeneous Chl a solution. Because both Chl a and pheophytin a molecules are effective for the photosensitive charge separation, the present film system is very suitable for heterogeneous immobilizing media for photosynthetic pigments from the viewpoint of in vitro biomimetic devices for solar energy conversion.
| 本文言語 | English |
|---|---|
| ページ（範囲） | 543-547 |
| ページ数 | 5 |
| ジャーナル | Journal of Sol-Gel Science and Technology |
| 巻 | 19 |
| 号 | 1-3 |
| DOI | |
| 出版ステータス | Published - 2000 12 1 |
| イベント | 10th International Workshop pn Glass and Ceramics, Hybrids and Nanocomposites from Gels - Yokohama, Jpn 継続期間: 1999 9 20 → 1999 9 24 |
ASJC Scopus subject areas
- Electronic, Optical and Magnetic Materials
- Ceramics and Composites
- Chemistry(all)
- Biomaterials
- Condensed Matter Physics
- Materials Chemistry