In situ investigations of polymer self-assembly solution adsorption by surface plasmon spectroscopy

Rigoberto Advincula*, Emil Aust, Wolfgang Meyer, Wolfgang Knoll

*この研究の対応する著者

研究成果査読

90 被引用数 (Scopus)

抄録

In this study, we report the use of surface plasmon spectroscopy (SPS) to investigate the self-assembly polymer solution adsorption process in situ. A sealed sample cell made of Teflon was assembled with the substrate initially coated with a positively charged surface using the Langmuir-Blodgett-Kuhn (LBK) deposition technique. The cationic and anionic polymer combinations were comprised mainly of a class of polyelectrolytes called ionenes and several anionic polymers. The solution adsorption process generally showed linear behavior except were the deviation is attributed to a poorly charged initial layer. The adsorption behavior is postulated to be due to conformational requirements and charge distribution of the individually adsorbed polymers. The time of adsorption for each polymer pair was also investigated. The technique promises to be an important tool in determining the mechanism for these types of adsorption processes.

本文言語English
ページ(範囲)3536-3540
ページ数5
ジャーナルLangmuir
12
15
出版ステータスPublished - 1996 7 24
外部発表はい

ASJC Scopus subject areas

  • 材料科学(全般)
  • 凝縮系物理学
  • 表面および界面
  • 分光学
  • 電気化学

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