In situ spectroscopy at the quasi-perfect pt(111) single-crystal facet|aqueous electrolyte interface

Iosif Fromondi, Huanfeng Zhu, Daniel Alberto Scherson*

*この研究の対応する著者

研究成果: Review article査読

7 被引用数 (Scopus)

抄録

The area of in situ spectroscopy at quasi-perfect Pt(111) single-crystal facet|aqueous electrolyte interfaces is herein reviewed. Illustrations are provided of the simultaneous application of differential reflectance spectroscopy and second-harmonic generation as static and dynamic probes of ionic and molecular adsorbates. Attention is focused on quantitative studies of bisulfate adsorption as well as of the dynamics of phase transitions and reactivity of carbon monoxide adlayers and their dependence on the applied potential. Also discussed are current limitations of these techniques, as well as possible means to improve their temporal and spatial resolution.

本文言語English
ページ(範囲)19613-19624
ページ数12
ジャーナルJournal of Physical Chemistry C
116
37
DOI
出版ステータスPublished - 2012 9 20
外部発表はい

ASJC Scopus subject areas

  • 電子材料、光学材料、および磁性材料
  • エネルギー(全般)
  • 物理化学および理論化学
  • 表面、皮膜および薄膜

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