In situ X-ray absorption of a carbon monoxide-iron porphyrin adduct adsorbed on high-area carbon in an aqueous electrolyte

In Tae Bae, Daniel Alberto Scherson*

*この研究の対応する著者

研究成果: Article査読

21 被引用数 (Scopus)

抄録

The electronic and electrochemical properties of a carbon monoxide-FeTMPP adduct (FeTMPP = (5,10,15,20-tetrakis[4-methoxyphenyl]-21H,23H-porphine)iron(II)) adsorbed on Black Pearls (BP) high-area carbon have been examined in situ in 0.05 M H2SO4 by Fe K-edge X-ray absorption near-edge structure (XANES). This adduct was prepared by first polarizing a Teflon bonded electrode, incorporating the high-area FeTMPP/BP material, at a potential at which the adsorbed macrocycle is present in the reduced state, followed by bubbling CO into the electrolyte. The resulting in situ XANES displayed two new preedge features centered at 7112 and 7115 eV, as found for other well-characterized iron macrocycle-CO adducts, as well as a shift of the main absorption edge toward higher values (ca. 1.3 V) indicative of charge transfer from the iron to CO. Dissociation of the adduct could be achieved by polarizing the electrode at more positive potentials to yield the CO-free form of the macrocycle in the ferric state, as has been reported for solution-phase CO-Fe porphyrin adducts in nonaqueous media.

本文言語English
ページ(範囲)2519-2522
ページ数4
ジャーナルJournal of Physical Chemistry B
102
14
出版ステータスPublished - 1998 4 2
外部発表はい

ASJC Scopus subject areas

  • 物理化学および理論化学
  • 表面、皮膜および薄膜
  • 材料化学

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