Incorporation of tris(2,2′-bipyridine)ruthenium(II) in a synthetic swelling mica with poly(vinylpyrrolidone)

Makoto Ogawa, Masashi Tsujimura, Kazuyuki Kuroda

    研究成果: Article

    30 引用 (Scopus)

    抄録

    Tris(2,2′-bipyridine)ruthenium(II) ([Ru(bpy)3]2+)-fluortetrasilicic mica-poly(vinylpyrrolidone) intercalation compounds were prepared by the intercalation of poly(vinylpyrrolidone) into the presynthesized [Ru(bpy)3]2+-fluortetrasilicic mica intercalation compounds. The formation of the intercalation compounds was confirmed by the expansion of the interlayer space as well as the spectroscopic observations. Intercalation compounds with variable chemical compositions have been prepared, and the effect of the distribution of the intercalated [Ru(bpy)3]2+ on the luminescence has been discussed. The luminescence probe can be utilized for the study of clay-polymer interactions.

    元の言語English
    ページ(範囲)4202-4206
    ページ数5
    ジャーナルLangmuir
    16
    発行部数9
    DOI
    出版物ステータスPublished - 2000 5 2

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    Intercalation compounds
    Ruthenium
    Mica
    mica
    intercalation
    swelling
    ruthenium
    Swelling
    Luminescence
    luminescence
    Intercalation
    Polymers
    Clay
    clays
    interlayers
    chemical composition
    Chemical analysis
    expansion
    probes
    polymers

    ASJC Scopus subject areas

    • Colloid and Surface Chemistry
    • Physical and Theoretical Chemistry

    これを引用

    Incorporation of tris(2,2′-bipyridine)ruthenium(II) in a synthetic swelling mica with poly(vinylpyrrolidone). / Ogawa, Makoto; Tsujimura, Masashi; Kuroda, Kazuyuki.

    :: Langmuir, 巻 16, 番号 9, 02.05.2000, p. 4202-4206.

    研究成果: Article

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    abstract = "Tris(2,2′-bipyridine)ruthenium(II) ([Ru(bpy)3]2+)-fluortetrasilicic mica-poly(vinylpyrrolidone) intercalation compounds were prepared by the intercalation of poly(vinylpyrrolidone) into the presynthesized [Ru(bpy)3]2+-fluortetrasilicic mica intercalation compounds. The formation of the intercalation compounds was confirmed by the expansion of the interlayer space as well as the spectroscopic observations. Intercalation compounds with variable chemical compositions have been prepared, and the effect of the distribution of the intercalated [Ru(bpy)3]2+ on the luminescence has been discussed. The luminescence probe can be utilized for the study of clay-polymer interactions.",
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    AU - Tsujimura, Masashi

    AU - Kuroda, Kazuyuki

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