Inorganic-Organic Layered Materials Derived via the Hydrolysis and Polycondensation of Trialkoxy(alkyl)silanes

Atsushi Shimojima, Yoshiyuki Sugahara, Kazuyuki Kuroda*

*この研究の対応する著者

研究成果: Article査読

139 被引用数 (Scopus)

抄録

Triethoxy(alkyl)silanes containing 12-18 carbon atoms in the alkyl groups were hydrolyzed and polycondensed to form ordered structured materials. The XRD pattern of each condensed product showed sharp diffraction peaks with higher orders. The basal spacings approximately corresponded to twice the extended molecular length of the alkyl groups, and increased linearly as a function of the alkyl chain length. The SEM images of the products exhibited a platy morphology, and the 29Si CP/MAS NMR spectra revealed the formation of siloxane bonds with various silicon sites from T1 to T3 environments. All of these results indicated the formation of highly-organized inorganic-organic layered materials.

本文言語English
ページ(範囲)2847-2853
ページ数7
ジャーナルBulletin of the Chemical Society of Japan
70
11
DOI
出版ステータスPublished - 1997 11

ASJC Scopus subject areas

  • 化学 (全般)

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