Intercalation characteristics of rhodamine 6G in fluor-taeniolite: Orientation in the gallery

Taketoshi Fujita*, Nobuo Iyi, Tetsushi Kosugi, Akitsugu Ando, Takahiro Deguchi, Takayuki Sota

*この研究の対応する著者

研究成果: Article査読

29 被引用数 (Scopus)

抄録

The orientation of rhodamine 6G (R6G) in the 22-Å basal-spaced complex with Li-fluortaeniolite has been studied using X-ray powder diffraction, 1-dimensional Fourier analysis, polarized infrared (IR) spectroscopy, carbon analysis and thermal analysis. The R6G was adsorbed by cation exchange in aqueous solution. In the range of 0.086 to 0,46 molar ratio of R6G to taeniolite, the basal spacings of the complex were nearly constant at 21.7 to 22.2 Å, From X-ray diffraction (XRD) data, it was confirmed that R6G in the complex orients with its longest xanthene ring axis perpendicular to the ab plane of the host. The pleochroism of IR absorption bands at 1331, 1517, 1537 and 1621 cm-1 supports the vertical orientation. The wide stability range of the vertical configuration is consistent with the strong coulombic force between the highly negatively charged silicate layer of the host [cation exchange capacity (CEC) = 157 ± 9 meq/100 g] and the positively charged nitrogen bonded to both sides of the R6G xanthene ring.

本文言語English
ページ(範囲)77-84
ページ数8
ジャーナルClays and Clay Minerals
45
1
DOI
出版ステータスPublished - 1997

ASJC Scopus subject areas

  • 水の科学と技術
  • 土壌科学
  • 地球化学および岩石学
  • 地球惑星科学(その他)

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