Intercalation of a nonionic surfactant (C10E3) bilayer into a Na-montmorillonite clay

Régis Guégan*

*この研究の対応する著者

研究成果: Article査読

55 被引用数 (Scopus)

抄録

A nonionic surfactant, triethylene glycol mono-n-decyl ether (C 10E3), characterized by its lamellar phase state, was introduced in the interlayer of a Na-montmorillonite clay at several concentrations. The synthesized organoclays were characterized by small-angle X-ray scattering in conjunction with Fourier transform infrared spectroscopy and adsorption isotherms. Experiments showed that a bilayer of C10E 3 was intercalated into the interlayer space of the naturally exchanged Na-montmorillonite, resulting in the aggregation of the lyotropic liquid crystal state in the lamellar phase. This behavior strongly differs from previous observations of confinement of nonionic surfactants in clays where the expansion of the interlayer space was limited to two monolayers parallel to the silicate surface and cationic surfactants in clays where the intercalation of organic compounds is introduced into the clay galleries through ion exchange. The confinement of a bilayer of C10E3 nonionic surfactant in clays offers new perspectives for the realization of hybrid nanomaterials, since the synthesized organoclays preserve the electrostatic characteristics of the clays, thus allowing further ion exchange while presenting at the same time a hydrophobic surface and a maximum opening of the interlayer space for the adsorption of neutral organic molecules of important size with functional properties.

本文言語English
ページ(範囲)19175-19180
ページ数6
ジャーナルLangmuir
26
24
DOI
出版ステータスPublished - 2010 12月 21
外部発表はい

ASJC Scopus subject areas

  • 材料科学(全般)
  • 凝縮系物理学
  • 表面および界面
  • 分光学
  • 電気化学

フィンガープリント

「Intercalation of a nonionic surfactant (C10E3) bilayer into a Na-montmorillonite clay」の研究トピックを掘り下げます。これらがまとまってユニークなフィンガープリントを構成します。

引用スタイル