Intercalation of tris(2,2′-bipyridme)ruthenium(II) into a layered silicate, magadiite, with the aid of a crown ether

Makoto Ogawa, Yoshinao Takizawa

研究成果: Article

27 引用 (Scopus)

抄録

Intercalation of the tris(2,2′-bipyridine)ruthenium(II) complex cation into a layered silicate (magadiite; the ideal formula is Na2Si14O29·nH2O) was investigated. Since the complex cation did not intercalate by a direct ion exchange reaction with the interlayer sodium ions in an aqueous medium, a crown ether, 15-crown-5, was added in the reactant to promote the ion-exchange reaction. Two possible reaction mechanisms were proposed for the present ion-exchange reaction: One is a two-step reaction, where 15-crown-5 was first intercalated into the interlayer space of Na-magadiite and exchanged with tris(2,2′-bipyridine)ruthenium(II) complex cation subsequently. The other is a one-step reaction, where 15-crown-5 forms complex ions with sodium ions deintercalated from the interlayer space and the tris(2,2′-bipyridine)ruthenium(II) complex cation is intercalated into the interlayer space to compensate the charge balance. The present success opens up new opportunities to introduce organic cations into the interlayer space of various layered solids.

元の言語English
ページ(範囲)5005-5009
ページ数5
ジャーナルJournal of Physical Chemistry B
103
発行部数24
出版物ステータスPublished - 1999 6 17

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Crown Ethers
Silicates
Crown ethers
Ruthenium
Intercalation
intercalation
ruthenium
Cations
ethers
silicates
Positive ions
interlayers
cations
Ion exchange
Ions
ions
Sodium
sodium
15-crown-5

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry

これを引用

Intercalation of tris(2,2′-bipyridme)ruthenium(II) into a layered silicate, magadiite, with the aid of a crown ether. / Ogawa, Makoto; Takizawa, Yoshinao.

:: Journal of Physical Chemistry B, 巻 103, 番号 24, 17.06.1999, p. 5005-5009.

研究成果: Article

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abstract = "Intercalation of the tris(2,2′-bipyridine)ruthenium(II) complex cation into a layered silicate (magadiite; the ideal formula is Na2Si14O29·nH2O) was investigated. Since the complex cation did not intercalate by a direct ion exchange reaction with the interlayer sodium ions in an aqueous medium, a crown ether, 15-crown-5, was added in the reactant to promote the ion-exchange reaction. Two possible reaction mechanisms were proposed for the present ion-exchange reaction: One is a two-step reaction, where 15-crown-5 was first intercalated into the interlayer space of Na-magadiite and exchanged with tris(2,2′-bipyridine)ruthenium(II) complex cation subsequently. The other is a one-step reaction, where 15-crown-5 forms complex ions with sodium ions deintercalated from the interlayer space and the tris(2,2′-bipyridine)ruthenium(II) complex cation is intercalated into the interlayer space to compensate the charge balance. The present success opens up new opportunities to introduce organic cations into the interlayer space of various layered solids.",
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