Intrachain Ferromagnetic Spin Alignment in π-Conjugated Polyradicals with a Poly(phenylenevinylene) Chain

Hiroyuki Nishide*

*この研究の対応する著者

研究成果査読

5 被引用数 (Scopus)

抄録

Poly(phenylenevinylene) was selected as a linear polymer-type magnetic coupler in polyradicals, because of its developed π-conjugation and solvent-solubility even after substitution on the phenylene ring. An intrachain and through-bond ferromagnetic interaction between the side-chain built-in radical groups was described for the chemically stable poly[4-(3′,5′-di-tert-butylphenoxy)-1,2-phenylenevinylene]. Effects of radical (spin) defects and molecular weight of the polyradical were discussed.

本文言語English
ページ(範囲)247-257
ページ数11
ジャーナルACS Symposium Series
644
出版ステータスPublished - 1996

ASJC Scopus subject areas

  • 化学 (全般)

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