@article{c8d02a4a56654bd78e938a7c205300ef,
title = "Intramolecular Consecutive Dehydro-Diels–Alder Reaction for the Catalytic and Enantioselective Construction of Axial Chirality",
abstract = "Consecutive thermal and metal-catalyzed dehydro-Diels–Alder (DDA) reactions of sulfur-tethered tetraynes, possessing a 1,3-diyne moiety, proceeded efficiently, and axial chirality was achieved for the resulting dibenzothiophenyl moieties. Chiral-rhodium catalysis realized a highly enantioselective synthesis, and transformations into bis(benzocarbazole) derivatives were also achieved.",
keywords = "axial chirality, cycloaddition, enantioselectivity, heterocycles, rhodium",
author = "Takanori Shibata and Ayato Sekine and Akihito Mitake and Kanyiva, {Kyalo Stephen}",
note = "Funding Information: This work was supported by Waseda University Grant for Special Research Projects. We are grateful to Umicore for generous support in the [RhCl(cod)]2 supply. Publisher Copyright: {\textcopyright} 2018 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim",
year = "2018",
month = nov,
day = "26",
doi = "10.1002/anie.201810174",
language = "English",
volume = "57",
pages = "15862--15865",
journal = "Angewandte Chemie - International Edition",
issn = "1433-7851",
publisher = "John Wiley and Sons Ltd",
number = "48",
}