Iridium-catalyzed enantioselective C-H alkylation of ferrocenes with alkenes using chiral diene ligands

Takanori Shibata, Tsubasa Shizuno

研究成果: Article査読

138 被引用数 (Scopus)

抄録

The first catalytic and enantioselective C-H alkylation of ferrocene derivatives with various alkenes was achieved. A cationic iridium complex, having a chiral diene ligand, and an isoquinolyl moiety as a directing group are essential for regioselective and enantioselective C-H bond activation. Director's cut: The first catalytic and enantioselective C-H alkylation of ferrocene derivatives with various alkenes was achieved. A cationic iridium complex, having a chiral diene ligand, and an isoquinolyl moiety as a directing group are essential for regioselective and enantioselective C-H bond activation. coe=cyclooctene, NaBARF=sodium tetrakis[3,5-bis(trifluoromethyl)phenyl]borate.

本文言語English
ページ(範囲)5410-5413
ページ数4
ジャーナルAngewandte Chemie - International Edition
53
21
DOI
出版ステータスPublished - 2014 5 19

ASJC Scopus subject areas

  • 触媒
  • 化学 (全般)

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