Iridium complex-catalyzed Pauson-Khand-type reaction of allenynes

Takanori Shibata; Sho Kadowaki; Masaya Hirase; Kentaro Takagi

doi:10.1055/s-2003-37532

Iridium complex-catalyzed Pauson-Khand-type reaction of allenynes

Takanori Shibata^*, Sho Kadowaki, Masaya Hirase, Kentaro Takagi

^*この研究の対応する著者

研究成果: Article › 査読

55 被引用数 (Scopus)

抄録

Vaska's complex [IrCl(CO)(PPh₃)₂] efficiently catalyzes the intramolecular carbonylative [2+2+1] cycloaddition of allenynes. A dimethyl substituent on the allene terminus and a low partial pressure of carbon monoxide realize the selective engagement of the internal π-bond of allene.

本文言語	English
ページ（範囲）	573-575
ページ数	3
ジャーナル	Synlett
号	4
DOI	https://doi.org/10.1055/s-2003-37532
出版ステータス	Published - 2003
外部発表	はい

ASJC Scopus subject areas

有機化学

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10.1055/s-2003-37532

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@article{3a72220f5838453180db18ee9187cdf2,

title = "Iridium complex-catalyzed Pauson-Khand-type reaction of allenynes",

abstract = "Vaska's complex [IrCl(CO)(PPh3)2] efficiently catalyzes the intramolecular carbonylative [2+2+1] cycloaddition of allenynes. A dimethyl substituent on the allene terminus and a low partial pressure of carbon monoxide realize the selective engagement of the internal π-bond of allene.",

keywords = "Alkynes, Allenes, Carbonylations, Iridium, Pauson-Khand reaction",

author = "Takanori Shibata and Sho Kadowaki and Masaya Hirase and Kentaro Takagi",

year = "2003",

doi = "10.1055/s-2003-37532",

language = "English",

pages = "573--575",

journal = "Synlett",

issn = "0936-5214",

publisher = "Georg Thieme Verlag",

number = "4",

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TY - JOUR

T1 - Iridium complex-catalyzed Pauson-Khand-type reaction of allenynes

AU - Shibata, Takanori

AU - Kadowaki, Sho

AU - Hirase, Masaya

AU - Takagi, Kentaro

PY - 2003

Y1 - 2003

N2 - Vaska's complex [IrCl(CO)(PPh3)2] efficiently catalyzes the intramolecular carbonylative [2+2+1] cycloaddition of allenynes. A dimethyl substituent on the allene terminus and a low partial pressure of carbon monoxide realize the selective engagement of the internal π-bond of allene.

AB - Vaska's complex [IrCl(CO)(PPh3)2] efficiently catalyzes the intramolecular carbonylative [2+2+1] cycloaddition of allenynes. A dimethyl substituent on the allene terminus and a low partial pressure of carbon monoxide realize the selective engagement of the internal π-bond of allene.

KW - Alkynes

KW - Allenes

KW - Carbonylations

KW - Iridium

KW - Pauson-Khand reaction

UR - http://www.scopus.com/inward/record.url?scp=0037237357&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0037237357&partnerID=8YFLogxK

U2 - 10.1055/s-2003-37532

DO - 10.1055/s-2003-37532

M3 - Article

AN - SCOPUS:0037237357

SP - 573

EP - 575

JO - Synlett

JF - Synlett

SN - 0936-5214

IS - 4

ER -

Iridium complex-catalyzed Pauson-Khand-type reaction of allenynes

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