Kinetics and mechanisms of inorganic and organometallic reactions of bis(amidato)-bridged cis-diammineplatinum(III) binuclear complexes: A review

Satoshi Iwatsuki*, Koji Ishihara, Kazuko Matsumoto

*この研究の対応する著者

研究成果: Review article査読

抄録

“Platinum blues”-derived bis(amidato)-bridged cis-diammineplatinum(III) binuclear (dimer) complexes, head-to-head (HH) and head-to-tail (HT) [Pt2(NH3)4(μ-amidato)2(OH2)2]4+ (amidato = α-pyridonato, α-pyrrolidonato, or pivalamidato), react with olefins and ketones via C–H bond activation at the axial site along the Pt–Pt bond to form organoplatinum(III) dimer complexes, which react further to form oxidized and/or hydroxylated products and the corresponding platinum(II) dimer complexes. Careful kinetic investigations have been carried out by our research group to understand the reactivities of the Pt(III) dimer complexes as potential catalysts for the oxidation of organic substrates. In this review, we focus on the kinetics of inorganic and organometallic reactions of the HH and HT bis(amidato)-bridged cis-diammine Pt(III) dimer complexes with halide ions, olefins, and ketones in acidic aqueous solutions, and discuss their detailed reaction mechanisms.

本文言語English
論文番号119888
ジャーナルInorganica Chimica Acta
512
DOI
出版ステータスPublished - 2020 11月 1

ASJC Scopus subject areas

  • 物理化学および理論化学
  • 無機化学
  • 材料化学

フィンガープリント

「Kinetics and mechanisms of inorganic and organometallic reactions of bis(amidato)-bridged cis-diammineplatinum(III) binuclear complexes: A review」の研究トピックを掘り下げます。これらがまとまってユニークなフィンガープリントを構成します。

引用スタイル