Living anionic polymerization of hexamethylcyclotrisiloxane (D 3) using functionalized initiation

Casey L. Elkins, Timothy Edward Long*

*この研究の対応する著者

研究成果: Article査読

28 被引用数 (Scopus)

抄録

A series of poly(dimethysiloxane) (PDMS) homopolymers were synthesized by living anionic polymerization using a protected amine functionalized initiator. Each functionalized initiator molecules had produced a macromolecule with the desired functionality at the chain end regardless to the molar mass of the polymer. The synthesis of PDMS homopolymers was done using 3-[(N-benzyl-N- methyl)-amino]-1-propyllithium. It was found that the protecting group was removed quantitively to yield a secondary amine functionality at the polymer chain end.

本文言語English
ページ(範囲)6657-6659
ページ数3
ジャーナルMacromolecules
37
17
DOI
出版ステータスPublished - 2004 8月 24
外部発表はい

ASJC Scopus subject areas

  • 材料化学

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