Major and trace element compositions and resource potential of ferromanganese crust at Takuyo Daigo Seamount, northwestern Pacific Ocean

Tatsuo Nozaki*, Ayaka Tokumaru, Yutaro Takaya, Yasuhiro Kato, Katsuhiko Suzuki, Tetsuro Urabe

*この研究の対応する著者

研究成果: Article査読

18 被引用数 (Scopus)

抄録

We report major element and trace element compositions of ferromanganese crusts (Fe-Mn crusts) on Takuyo Daigo Seamount, northwestern Pacific Ocean. Highly enriched elements in these crusts, such as Co (6500 ppm), Ni (4000 ppm), Mo (520 ppm), Te (39 ppm), W (92 ppm), Pt (0.19 ppm), and rare earth elements (REEs; ΣREE = 1700 ppm), exhibit strong positive correlations with either Fe or Mn concentrations. Chemical analyses of the crusts show that the Fe/Mn ratio decreases toward shallower water and older deposits. Thus, deeper or younger crust is more promising as a REE (other than Ce) resource, and shallower or older crust has a greater potential as Co, Ni, Ce, and Pt resources. REE profiles of Fe-Mn crusts with less than 0.5 wt% P, normalized to post-Archean average Australian shale, are flat with positive Ce anomalies whereas samples with more than 0.5 wt% P are enriched in heavy REE, and four samples from deep in the crusts with more than 2.2 wt% P do not exhibit positive Ce anomalies. These differences in REE patterns can be explained by mixing of Fe-Mn oxide and Ca-phosphate minerals (apatite). Assuming that Fe-Mn crusts with 5 cm thickness and 1.29 g/cm3 dry density are homogeneously distributed at water depths from 1000 to 3000 m along the 500 km perimeter of Takuyo Daigo Seamount, the possible reserve represented by Fe-Mn crusts is roughly 65 Mt of ore. Based on the average concentrations obtained here, resource amounts at Takuyo Daigo Seamount are 420 ×103 t Co, 110 ×103 tREO, 2500 t Dy, and 440 t Tb, comparable to the known reserves of major mineral producing nations. Thus, Fe-Mn crusts in the northwestern Pacific Ocean have a notable potential as a source of Co.

本文言語English
ページ(範囲)527-537
ページ数11
ジャーナルGEOCHEMICAL JOURNAL
50
6
DOI
出版ステータスPublished - 2016

ASJC Scopus subject areas

  • 地球物理学
  • 地球化学および岩石学

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