Matrix-isolation infrared and ultraviolet spectroscopic studies of less stable conformers of 1,3,5-hexatriene

Y. Furukawa, H. Takeuchi, I. Harada, M. Tasumi

研究成果: Article査読

40 被引用数 (Scopus)

抄録

The infrared spectra of the 3-trans and 3-cis isomers of 1,3,5-hexatriene in low-temperature Ar matrices deposited from a high-temperature nozzle or deposited under irradiation of the Hg 253.7 nm light show a number of new bands. Correspondingly, the ultraviolet spectra of the 3-trans isomer observed under similar experimental conditions show a new absorption at 276 nm. Most of these new infrared bands and the new ultraviolet absorption are attributable to less stable isomers which have the planar s-cis conformation [or gauche conformation(s) close to the planar s-cis] about either one or both of the two CC bonds.

本文言語English
ページ(範囲)341-350
ページ数10
ジャーナルJournal of Molecular Structure
100
C
DOI
出版ステータスPublished - 1983 7
外部発表はい

ASJC Scopus subject areas

  • Analytical Chemistry
  • Spectroscopy
  • Organic Chemistry
  • Inorganic Chemistry

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