Measurement of circular dichroism of ferroelectric fresnoite Ba 2Si2TiO8

Toni Asahi*, Tetsuya Osaka, Sidney C. Abrahamsb, Ryo Matsuki, Hiroshi Asai, Satoshi Nanamatsu, Jinzo Kobayashi

*この研究の対応する著者

研究成果: Conference article査読

4 被引用数 (Scopus)

抄録

The urgent goal of the optical polarimetry of solids is simultaneous and accurate measurements of circular dichroism together with circular birefringence. Needless to say, measurements of circular phenomena are extremely difficult compared with those of linear ones. As for circular birefringence, 170 years elapsed since its discovery by Arago until the development of the HAUP method, by which the accurate measurements of the gyration tensor components of a solid became possible for the first time. Subsequent to appearance of the HAUP method, attempts to extend the HAUP theory to being applicable for measurements of circular dichroism of crystals were followed by several authors. However any applications to real crystal were not fully successful. We completed fresh the theory of the extended HAUP. This paper reports the extended HAUP measurement of both circular birefringence and dichroism of fresnoite Ba2Si2TiO8. It is clearly found that the circular dichroism abruptly appears at the transition temperature, where the crystal changes from the high temperature 4mm phase to the low temperature mm2 phase. It increases with decrease of temperature together with circular birefringence. This is the first proof that the HAUP method provides with sufficiently accurate data of circular dichroism of crystals. It is important to note that the circular dichroism affects only θ0, which is one of the salient parameter characterizing the HAUP method. It means that the HAUP is an exclusive method for measuring circular dichroism of crystals.

本文言語English
ページ(範囲)223-232
ページ数10
ジャーナルProceedings of SPIE - The International Society for Optical Engineering
5218
DOI
出版ステータスPublished - 2003 12 1
イベントPROCEEDINGS OF SPIE SPIE - The International Society for Optical Engineering: Complex Mediums IV: Beyond Linear Isotropic Dielectrics - San Diego, CA, United States
継続期間: 2003 8 42003 8 5

ASJC Scopus subject areas

  • 電子材料、光学材料、および磁性材料
  • 凝縮系物理学
  • コンピュータ サイエンスの応用
  • 応用数学
  • 電子工学および電気工学

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