Measurement of NO2 by the photolysis conversion technique during the Transport and Chemical Evolution Over the Pacific (TRACE-P) campaign

K. Nakamura*, Y. Kondo, G. Chen, J. H. Crawford, N. Takegawa, M. Koike, K. Kita, Y. Miyazaki, R. E. Shetter, B. L. Lefer, M. Avery, J. Matsumoto

*この研究の対応する著者

研究成果: Article査読

14 被引用数 (Scopus)

抄録

An airborne instrument for in situ measurements of tropospheric nitrogen dioxide (NO2) was developed using the photolytic conversion technique followed by chemiluminescence detection of NO. This instrument was used for the measurements of NO2 on board the NASA P-3B aircraft during the Transport and Chemical Evolution Over the Pacific (TRACE-P) campaign. Comparison in the laboratory indicated less than 10% difference between our NO2 instrument and two independent laser-induced fluorescence instruments in the NO2 range of 30 parts per trillion by volume (pptv) to 50 ppbv. The magnitudes of potential errors in airborne tropospheric NO2 measurements were further assessed using the TRACE-P data set. The systematic errors estimated for the median NO2 mixing ratios, 70 pptv at 0-2 km (30 pptv at 2 8 km), were 19% (39%). The random errors for a 10 s integration time were estimated to be 5-10%, depending on altitude. The observed NO2 mixing ratios were compared to those calculated by a photochemical box model. Overall, the calculated NO2 values correlated very well with those observed (r2 = 0.97), although the calculations were systematically higher than the observations by about 30%, except for the highest flight levels. The calculated/ observed NO2 ratio remained nearly constant, having values close to 1.3 at 0-4 km, and decreased with altitude. The difference between the observed and model-calculated values, however, was within the combined uncertainty in the measurement and model calculation. The underlying causes for this difference are to be determined in future studies.

本文言語English
ページ(範囲)ACH 1-1 - ACH 1-11
ジャーナルJournal of Geophysical Research: Atmospheres
108
24
DOI
出版ステータスPublished - 2003 12月 27
外部発表はい

ASJC Scopus subject areas

  • 地球物理学
  • 林業
  • 海洋学
  • 水圏科学
  • 生態学
  • 水の科学と技術
  • 土壌科学
  • 地球化学および岩石学
  • 地表過程
  • 大気科学
  • 地球惑星科学(その他)
  • 宇宙惑星科学
  • 古生物学

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