Mechanism of nanocrystalline microstructure formation in amorphous Fe-Nb-B alloys

Akihiko Hirata*, Yoshihiko Hirotsu, Eiichiro Matsubara, Tadakatsu Ohkubo, Kazuhiro Hono


研究成果: Article査読

36 被引用数 (Scopus)


To understand the mechanism of the high number density of bcc-Fe nanocrystals in a partially crystallized Fe84 Nb7 B9 alloy, we have investigated detailed local structural and compositional changes on annealing amorphous ribbons using transmission electron microscopy, three-dimensional atom probe, and high-energy x-ray diffraction techniques. Nanobeam electron diffraction patterns from an as-quenched amorphous ribbon indicated a local nanoscale atomic ordering. On annealing, reduced interference functions showed a clear change just below the crystallization temperature (∼773 K). At this stage, local compositional fluctuations started to appear, and medium-range ordering with a bcc-Fe structure as small as 2 nm was clearly observed in high-resolution electron micrographs with an extremely high number density. Pair distribution function analyses suggested a structural change at this stage of annealing to increase the chemical bonds in the residual amorphous matrix around the bcc-Fe regions. The increase of atomic chemical bonds in the residual amorphous matrix is considered to retard the growth of the bcc-Fe nanocrystals after the coalescence of bcc-Fe MRO regions in the later stage of annealing. These results suggest that bcc-Fe nanocrystallization with the extremely high number density is ascribed to primarily (i) the presence of highly dense bcc-Fe MRO regions and (ii) the increase of chemical bonds of matrix atoms on annealing.

ジャーナルPhysical Review B - Condensed Matter and Materials Physics
出版ステータスPublished - 2006 11月 23

ASJC Scopus subject areas

  • 電子材料、光学材料、および磁性材料
  • 凝縮系物理学


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