Mechanochromic Dynamic Covalent Elastomers: Quantitative Stress Evaluation and Autonomous Recovery

Keiichi Imato, Takeshi Kanehara, Tomoyuki Ohishi, Masamichi Nishihara, Hirofumi Yajima, Masayoshi Ito, Atsushi Takahara, Hideyuki Otsuka

研究成果: Article

69 引用 (Scopus)

抜粋

Stress evaluation in polymeric materials is important in order to not only spot danger in them before serious failure, but also precisely interpret the destructive mechanism, which can improve the lifetime and durability of polymeric materials. Here, we are able to visualize stress by color changes, as well as quantitatively estimate the stress in situ, in segmented polyurethane elastomers with diarylbibenzofuranone-based dynamic covalent mechanophores. We prepared films of the segmented polyurethanes, in which the mechanophores were incorporated in the soft segments, and efficiently activated them by mechanical force. Cleavage of the mechanophores during uniaxial elongation and their recovery after the removal of the stress were quantitatively evaluated by in situ electron paramagnetic resonance measurements, accompanied by drastic color changes.

元の言語English
ページ(範囲)1307-1311
ページ数5
ジャーナルACS Macro Letters
4
発行部数11
DOI
出版物ステータスPublished - 2015 11 9
外部発表Yes

ASJC Scopus subject areas

  • Organic Chemistry
  • Materials Chemistry
  • Polymers and Plastics
  • Inorganic Chemistry

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  • これを引用

    Imato, K., Kanehara, T., Ohishi, T., Nishihara, M., Yajima, H., Ito, M., Takahara, A., & Otsuka, H. (2015). Mechanochromic Dynamic Covalent Elastomers: Quantitative Stress Evaluation and Autonomous Recovery. ACS Macro Letters, 4(11), 1307-1311. https://doi.org/10.1021/acsmacrolett.5b00717