Metal-Ion Adsorption on Poly(1-vinylimidazole) Resins Prepared by γ-Irradiation with Template Metal Ion

Masayuki Kato, Hiroyuki Nishide, Eishun Tsuchida, Takashi Sasaki

研究成果: Article

抄録

Poly (1-vinylimidazole) (PVI) resins were prepared with a metal ion as template by the radiation polymerization at room temperature. The metal (Ni2+, Co2+ and Zn2+)-1-vinylimidazole complex was copolymerized and crosslinked with 1-vinylpyrrolidone by γ-ray irradiation, followed by the removal of the template metal ion by treating the resins with an acid. These PVI resins adsorbed metal ions in the wide pH region more effectively than the PVI resins prepared without template, which is due to an increase in the number of adsorption sites (A8) and the larger stability constants (K) of the PVI resins prepared with template.

元の言語English
ページ(範囲)647-650
ページ数4
ジャーナルKobunshi Ronbunshu
37
発行部数10
DOI
出版物ステータスPublished - 1980

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Metal ions
resin
irradiation
Resins
Irradiation
adsorption
Adsorption
ion
metal
polymerization
Metals
Polymerization
poly(1-vinylimidazole)
Radiation
Acids
acid
temperature
Temperature

ASJC Scopus subject areas

  • Chemical Engineering (miscellaneous)
  • Materials Science (miscellaneous)
  • Environmental Science(all)
  • Polymers and Plastics

これを引用

Metal-Ion Adsorption on Poly(1-vinylimidazole) Resins Prepared by γ-Irradiation with Template Metal Ion. / Kato, Masayuki; Nishide, Hiroyuki; Tsuchida, Eishun; Sasaki, Takashi.

:: Kobunshi Ronbunshu, 巻 37, 番号 10, 1980, p. 647-650.

研究成果: Article

Kato, Masayuki ; Nishide, Hiroyuki ; Tsuchida, Eishun ; Sasaki, Takashi. / Metal-Ion Adsorption on Poly(1-vinylimidazole) Resins Prepared by γ-Irradiation with Template Metal Ion. :: Kobunshi Ronbunshu. 1980 ; 巻 37, 番号 10. pp. 647-650.
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AU - Tsuchida, Eishun

AU - Sasaki, Takashi

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KW - Radiation Polymerization

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