Microstructure and Oxidation Performance of TiAl-(Cr, Nb, Ta) Coatings Fabricated by Warm Spray and High-Velocity Oxy-Fuel Spraying

Judyta Sienkiewicz, Seiji Kuroda, Hideyuki Murakami, Hiroshi Araki, Maciej Giżyński, Krzysztof J. Kurzydłowski

研究成果: Article

抄録

To improve the oxidation resistance of near α-titanium alloy IMI834, TiAl-(Cr, Nb, Ta) coatings were deposited by applying high-velocity oxy-fuel (HVOF) and warm spray (WS). Comparison was made in terms of microstructure, surface morphology as well as isothermal and cyclic oxidation behaviors in the air at 750 °C up to 100 h and 100 cycles, respectively. The results show that smoother and less oxidized coatings were deposited by warm spraying. The microstructure of all coatings underwent an appreciable change during the oxidation tests, as in as-sprayed state it occurred in the nonequilibrium state. It was revealed that a small difference in the initial oxidation between the two spraying processes as well as microstructure, the level of porosity and surface roughness significantly influences the oxidation kinetics of the sprayed coatings at high temperature, which should affect the service lifetime as an oxidation-resistant layer for potential applications. After exposure at 750 °C in air, rutile TiO 2 was found in addition to α-Al 2 O 3 in the oxide scale formed on the HVOF and warm sprayed coatings. However, isothermal and cyclic oxidation tests of all WS TiAl-(Cr, Nb, Ta) coatings showed improved oxidation resistance of IMI 834 as well as good adherence to the substrate alloy.

元の言語English
ページ(範囲)563-579
ページ数17
ジャーナルJournal of Thermal Spray Technology
28
発行部数3
DOI
出版物ステータスPublished - 2019 2 15
外部発表Yes

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HVOF thermal spraying
Spraying
sprayers
coatings
Coatings
Oxidation
microstructure
Microstructure
oxidation
sprayed coatings
Sprayed coatings
oxidation resistance
spraying
Oxidation resistance
air
titanium alloys
Air
Titanium alloys
rutile
Oxides

ASJC Scopus subject areas

  • Condensed Matter Physics
  • Surfaces, Coatings and Films
  • Materials Chemistry

これを引用

Microstructure and Oxidation Performance of TiAl-(Cr, Nb, Ta) Coatings Fabricated by Warm Spray and High-Velocity Oxy-Fuel Spraying. / Sienkiewicz, Judyta; Kuroda, Seiji; Murakami, Hideyuki; Araki, Hiroshi; Giżyński, Maciej; Kurzydłowski, Krzysztof J.

:: Journal of Thermal Spray Technology, 巻 28, 番号 3, 15.02.2019, p. 563-579.

研究成果: Article

Sienkiewicz, Judyta ; Kuroda, Seiji ; Murakami, Hideyuki ; Araki, Hiroshi ; Giżyński, Maciej ; Kurzydłowski, Krzysztof J. / Microstructure and Oxidation Performance of TiAl-(Cr, Nb, Ta) Coatings Fabricated by Warm Spray and High-Velocity Oxy-Fuel Spraying. :: Journal of Thermal Spray Technology. 2019 ; 巻 28, 番号 3. pp. 563-579.
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abstract = "To improve the oxidation resistance of near α-titanium alloy IMI834, TiAl-(Cr, Nb, Ta) coatings were deposited by applying high-velocity oxy-fuel (HVOF) and warm spray (WS). Comparison was made in terms of microstructure, surface morphology as well as isothermal and cyclic oxidation behaviors in the air at 750 °C up to 100 h and 100 cycles, respectively. The results show that smoother and less oxidized coatings were deposited by warm spraying. The microstructure of all coatings underwent an appreciable change during the oxidation tests, as in as-sprayed state it occurred in the nonequilibrium state. It was revealed that a small difference in the initial oxidation between the two spraying processes as well as microstructure, the level of porosity and surface roughness significantly influences the oxidation kinetics of the sprayed coatings at high temperature, which should affect the service lifetime as an oxidation-resistant layer for potential applications. After exposure at 750 °C in air, rutile TiO 2 was found in addition to α-Al 2 O 3 in the oxide scale formed on the HVOF and warm sprayed coatings. However, isothermal and cyclic oxidation tests of all WS TiAl-(Cr, Nb, Ta) coatings showed improved oxidation resistance of IMI 834 as well as good adherence to the substrate alloy.",
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