Mixed-valence state of a pyrazine-bridged dimer of oxocarboxylatotriruthenium complexes with a nitrosyl ligand

Hiroyoshi Ohtsu, Naoya Fujiwara, Tadashi Yamaguchi

    研究成果: Article

    10 引用 (Scopus)

    抄録

    Three new pyrazine-bridged dimers of oxoacetatotriruthenium with an NO ligand are synthesized. These complexes show two types of stable mixed-valence states. The ν(NO) stretches for five oxidation states were obtained, and the intramolecular electron-transfer rate within the mixed-valence state is evaluated from the IR spectral line-shape simulation based on Bloch-type analysis, which is the first application of this method to a spectator ligand of NO.

    元の言語English
    ページ（範囲）7382-7384
    ページ数3
    ジャーナルInorganic Chemistry
    巻50
    発行部数16
    DOI
    出版物ステータスPublished - 2011 8 15

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    Pyrazines
    pyrazines
    Dimers
    dimers
    Ligands
    valence
    ligands
    line spectra
    line shape
    electron transfer
    Oxidation
    oxidation
    Electrons
    simulation

    ASJC Scopus subject areas

    • Inorganic Chemistry
    • Physical and Theoretical Chemistry

    これを引用

    Mixed-valence state of a pyrazine-bridged dimer of oxocarboxylatotriruthenium complexes with a nitrosyl ligand. / Ohtsu, Hiroyoshi; Fujiwara, Naoya; Yamaguchi, Tadashi.

    ：: Inorganic Chemistry, 巻 50, 番号 16, 15.08.2011, p. 7382-7384.

    研究成果: Article

    Ohtsu, H, Fujiwara, N & Yamaguchi, T 2011, 'Mixed-valence state of a pyrazine-bridged dimer of oxocarboxylatotriruthenium complexes with a nitrosyl ligand', Inorganic Chemistry, 巻. 50, 番号 16, pp. 7382-7384. https://doi.org/10.1021/ic201246m
    Ohtsu H, Fujiwara N, Yamaguchi T. Mixed-valence state of a pyrazine-bridged dimer of oxocarboxylatotriruthenium complexes with a nitrosyl ligand. Inorganic Chemistry. 2011 8 15;50(16):7382-7384. https://doi.org/10.1021/ic201246m
    Ohtsu, Hiroyoshi ; Fujiwara, Naoya ; Yamaguchi, Tadashi. / Mixed-valence state of a pyrazine-bridged dimer of oxocarboxylatotriruthenium complexes with a nitrosyl ligand. ：: Inorganic Chemistry. 2011 ; 巻 50, 番号 16. pp. 7382-7384.
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