抄録
Three new pyrazine-bridged dimers of oxoacetatotriruthenium with an NO ligand are synthesized. These complexes show two types of stable mixed-valence states. The ν(NO) stretches for five oxidation states were obtained, and the intramolecular electron-transfer rate within the mixed-valence state is evaluated from the IR spectral line-shape simulation based on Bloch-type analysis, which is the first application of this method to a spectator ligand of NO.
本文言語 | English |
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ページ(範囲) | 7382-7384 |
ページ数 | 3 |
ジャーナル | Inorganic Chemistry |
巻 | 50 |
号 | 16 |
DOI | |
出版ステータス | Published - 2011 8月 15 |
ASJC Scopus subject areas
- 物理化学および理論化学
- 無機化学