Mixed-valence state of a pyrazine-bridged dimer of oxocarboxylatotriruthenium complexes with a nitrosyl ligand

Hiroyoshi Ohtsu, Naoya Fujiwara, Tadashi Yamaguchi*

*この研究の対応する著者

研究成果: Article査読

10 被引用数 (Scopus)

抄録

Three new pyrazine-bridged dimers of oxoacetatotriruthenium with an NO ligand are synthesized. These complexes show two types of stable mixed-valence states. The ν(NO) stretches for five oxidation states were obtained, and the intramolecular electron-transfer rate within the mixed-valence state is evaluated from the IR spectral line-shape simulation based on Bloch-type analysis, which is the first application of this method to a spectator ligand of NO.

本文言語English
ページ(範囲)7382-7384
ページ数3
ジャーナルInorganic Chemistry
50
16
DOI
出版ステータスPublished - 2011 8月 15

ASJC Scopus subject areas

  • 物理化学および理論化学
  • 無機化学

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