Mixed-valence state of a pyrazine-bridged dimer of oxocarboxylatotriruthenium complexes with a nitrosyl ligand

Hiroyoshi Ohtsu; Naoya Fujiwara; Tadashi Yamaguchi

doi:10.1021/ic201246m

Mixed-valence state of a pyrazine-bridged dimer of oxocarboxylatotriruthenium complexes with a nitrosyl ligand

Hiroyoshi Ohtsu, Naoya Fujiwara, Tadashi Yamaguchi^*

^*この研究の対応する著者

先進理工学部

研究成果: Article › 査読

10 被引用数 (Scopus)

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Three new pyrazine-bridged dimers of oxoacetatotriruthenium with an NO ligand are synthesized. These complexes show two types of stable mixed-valence states. The ν(NO) stretches for five oxidation states were obtained, and the intramolecular electron-transfer rate within the mixed-valence state is evaluated from the IR spectral line-shape simulation based on Bloch-type analysis, which is the first application of this method to a spectator ligand of NO.

本文言語	English
ページ（範囲）	7382-7384
ページ数	3
ジャーナル	Inorganic Chemistry
巻	50
号	16
DOI	https://doi.org/10.1021/ic201246m
出版ステータス	Published - 2011 8月 15

ASJC Scopus subject areas

物理化学および理論化学
無機化学

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10.1021/ic201246m

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abstract = "Three new pyrazine-bridged dimers of oxoacetatotriruthenium with an NO ligand are synthesized. These complexes show two types of stable mixed-valence states. The ν(NO) stretches for five oxidation states were obtained, and the intramolecular electron-transfer rate within the mixed-valence state is evaluated from the IR spectral line-shape simulation based on Bloch-type analysis, which is the first application of this method to a spectator ligand of NO.",

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AU - Yamaguchi, Tadashi

PY - 2011/8/15

Y1 - 2011/8/15

N2 - Three new pyrazine-bridged dimers of oxoacetatotriruthenium with an NO ligand are synthesized. These complexes show two types of stable mixed-valence states. The ν(NO) stretches for five oxidation states were obtained, and the intramolecular electron-transfer rate within the mixed-valence state is evaluated from the IR spectral line-shape simulation based on Bloch-type analysis, which is the first application of this method to a spectator ligand of NO.

AB - Three new pyrazine-bridged dimers of oxoacetatotriruthenium with an NO ligand are synthesized. These complexes show two types of stable mixed-valence states. The ν(NO) stretches for five oxidation states were obtained, and the intramolecular electron-transfer rate within the mixed-valence state is evaluated from the IR spectral line-shape simulation based on Bloch-type analysis, which is the first application of this method to a spectator ligand of NO.

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Mixed-valence state of a pyrazine-bridged dimer of oxocarboxylatotriruthenium complexes with a nitrosyl ligand

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