Modeling of oxidation process and property changes of ethylene-propylene-diene copolymer

Daomin Min, Shengtao Li, Naoshi Hirai, Yoshimichi Ohki

研究成果: Article

2 引用 (Scopus)

抄録

The oxidation process induced in ethylene-propylene-diene (EPDM) copolymer by gamma irradiation was simulated by solving equations on chemical reactions and gas diffusion rates. As a result, distributions of oxidative products and gases and changes in material properties were clarified. All the oxidative products such as ketones, alcohols, and carboxylic acids, crosslinks between molecular chains, and chain scissions in EPDM increase with irradiation and they show concave spatial distributions inside the sample sheets. The simulation results demonstrates that EPDM becomes hard when it was irradiated by gamma rays and the increase in hardness is more significant at the surface of the sample sheet than its inside. Moreover, it was found that a low diffusion coefficient of oxygen in EPDM leads to the appearance of a clearer diffusion-limited regime of degradation. These simulation results are in good agreement with experimental results.

元の言語English
記事番号7422602
ページ(範囲)537-546
ページ数10
ジャーナルIEEE Transactions on Dielectrics and Electrical Insulation
23
発行部数1
DOI
出版物ステータスPublished - 2016 2 1

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Propylene
Ethylene
Copolymers
Irradiation
Oxidation
Diffusion in gases
Ketones
Carboxylic acids
Gamma rays
Spatial distribution
Chemical reactions
Materials properties
Alcohols
Hardness
Degradation
Oxygen
Gases

ASJC Scopus subject areas

  • Electrical and Electronic Engineering

これを引用

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