More Peptides and Other Diverse Constituents of the Marine Mollusk Philinopsis speciosa

Yoichi Nakao, Wesley Y. Yoshida, Christina M. Szabo, Bill J. Baker, Paul J. Scheuer*

*この研究の対応する著者

研究成果: Article査読

60 被引用数 (Scopus)

抄録

In addition to five new depsipeptides related to kulolide-1 (1), further examination of the mollusk Philinopsis speciosa has yielded a linear peptide, pupukeamide (14), and an unprecedented macrolide, tolytoxin-23-acetate (7). Chemical makeup suggested that the compounds originate from blue-green algae and are transmitted via herbivorous mollusks to P. speciosa. This could be verified by laboratory experiment. The structures were determined largely by spectroscopic techniques and the stereochemistry by hydrolysis of the peptides followed by chiral chromatography.

本文言語English
ページ(範囲)3272-3280
ページ数9
ジャーナルJournal of Organic Chemistry
63
10
DOI
出版ステータスPublished - 1998 5月 15
外部発表はい

ASJC Scopus subject areas

  • 有機化学

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