Multicomponent-Reaction-Ready Biomass-Sourced Organic Hybrids Fabricated via the Surface Immobilization of Polymers with Lignin-Based Compounds

Takashi Hamada*, Shuhei Yamashita, Masaaki Omichi, Kimio Yoshimura, Yuji Ueki, Noriaki Seko, Ryohei Kakuchi

*この研究の対応する著者

研究成果: Article査読

13 被引用数 (Scopus)

抄録

Compounds derived from two major biomass components, cellulose and lignin, were artificially recombined via the radiation-induced graft polymerization of vinyl monomers, which could be potentially sourced from lignin, onto cellulose fabric. This process yielded organic hybrids featuring a cellulose substrate and surface aldehyde groups from lignin-obtained vanillin. Then, the surface Kabachnik-Fields three-component reaction (KF-3CR) of poly(methacrylated vanillin) (PMV)-sourced aldehydes was carried out with amines and phosphites. Overall, the surface KF-3CR on the cellulose fabric grafted with PMV represents a facile preparation of multifunctional molecules on cellulose surfaces along with α-amino phosphonate ester integrations.

本文言語English
ページ(範囲)7795-7803
ページ数9
ジャーナルACS Sustainable Chemistry and Engineering
7
8
DOI
出版ステータスPublished - 2019 4月 15
外部発表はい

ASJC Scopus subject areas

  • 化学 (全般)
  • 環境化学
  • 化学工学(全般)
  • 再生可能エネルギー、持続可能性、環境

フィンガープリント

「Multicomponent-Reaction-Ready Biomass-Sourced Organic Hybrids Fabricated via the Surface Immobilization of Polymers with Lignin-Based Compounds」の研究トピックを掘り下げます。これらがまとまってユニークなフィンガープリントを構成します。

引用スタイル