Multicomponent-Reaction-Ready Biomass-Sourced Organic Hybrids Fabricated via the Surface Immobilization of Polymers with Lignin-Based Compounds

Takashi Hamada; Shuhei Yamashita; Masaaki Omichi; Kimio Yoshimura; Yuji Ueki; Noriaki Seko; Ryohei Kakuchi

doi:10.1021/acssuschemeng.8b06812

Multicomponent-Reaction-Ready Biomass-Sourced Organic Hybrids Fabricated via the Surface Immobilization of Polymers with Lignin-Based Compounds

Takashi Hamada^*, Shuhei Yamashita, Masaaki Omichi, Kimio Yoshimura, Yuji Ueki, Noriaki Seko, Ryohei Kakuchi

^*この研究の対応する著者

研究成果: Article › 査読

13 被引用数 (Scopus)

抄録

Compounds derived from two major biomass components, cellulose and lignin, were artificially recombined via the radiation-induced graft polymerization of vinyl monomers, which could be potentially sourced from lignin, onto cellulose fabric. This process yielded organic hybrids featuring a cellulose substrate and surface aldehyde groups from lignin-obtained vanillin. Then, the surface Kabachnik-Fields three-component reaction (KF-3CR) of poly(methacrylated vanillin) (PMV)-sourced aldehydes was carried out with amines and phosphites. Overall, the surface KF-3CR on the cellulose fabric grafted with PMV represents a facile preparation of multifunctional molecules on cellulose surfaces along with α-amino phosphonate ester integrations.

本文言語	English
ページ（範囲）	7795-7803
ページ数	9
ジャーナル	ACS Sustainable Chemistry and Engineering
巻	7
号	8
DOI	https://doi.org/10.1021/acssuschemeng.8b06812
出版ステータス	Published - 2019 4月 15
外部発表	はい

ASJC Scopus subject areas

化学 (全般)
環境化学
化学工学（全般）
再生可能エネルギー、持続可能性、環境

文献へのアクセス

10.1021/acssuschemeng.8b06812

他のファイルとリンク

フィンガープリント

「Multicomponent-Reaction-Ready Biomass-Sourced Organic Hybrids Fabricated via the Surface Immobilization of Polymers with Lignin-Based Compounds」の研究トピックを掘り下げます。これらがまとまってユニークなフィンガープリントを構成します。

引用スタイル

@article{8a3fcbe5bb87432b983dbdb4d4ba531b,

title = "Multicomponent-Reaction-Ready Biomass-Sourced Organic Hybrids Fabricated via the Surface Immobilization of Polymers with Lignin-Based Compounds",

abstract = "Compounds derived from two major biomass components, cellulose and lignin, were artificially recombined via the radiation-induced graft polymerization of vinyl monomers, which could be potentially sourced from lignin, onto cellulose fabric. This process yielded organic hybrids featuring a cellulose substrate and surface aldehyde groups from lignin-obtained vanillin. Then, the surface Kabachnik-Fields three-component reaction (KF-3CR) of poly(methacrylated vanillin) (PMV)-sourced aldehydes was carried out with amines and phosphites. Overall, the surface KF-3CR on the cellulose fabric grafted with PMV represents a facile preparation of multifunctional molecules on cellulose surfaces along with α-amino phosphonate ester integrations.",

keywords = "Amino phosphonates, Cellulose, Lignin-sourced, Multicomponent reactions, Organic hybrids",

author = "Takashi Hamada and Shuhei Yamashita and Masaaki Omichi and Kimio Yoshimura and Yuji Ueki and Noriaki Seko and Ryohei Kakuchi",

note = "Publisher Copyright: {\textcopyright} 2019 American Chemical Society.",

year = "2019",

month = apr,

day = "15",

doi = "10.1021/acssuschemeng.8b06812",

language = "English",

volume = "7",

pages = "7795--7803",

journal = "ACS Sustainable Chemistry and Engineering",

issn = "2168-0485",

publisher = "American Chemical Society",

number = "8",

}

TY - JOUR

T1 - Multicomponent-Reaction-Ready Biomass-Sourced Organic Hybrids Fabricated via the Surface Immobilization of Polymers with Lignin-Based Compounds

AU - Hamada, Takashi

AU - Yamashita, Shuhei

AU - Omichi, Masaaki

AU - Yoshimura, Kimio

AU - Ueki, Yuji

AU - Seko, Noriaki

AU - Kakuchi, Ryohei

PY - 2019/4/15

Y1 - 2019/4/15

N2 - Compounds derived from two major biomass components, cellulose and lignin, were artificially recombined via the radiation-induced graft polymerization of vinyl monomers, which could be potentially sourced from lignin, onto cellulose fabric. This process yielded organic hybrids featuring a cellulose substrate and surface aldehyde groups from lignin-obtained vanillin. Then, the surface Kabachnik-Fields three-component reaction (KF-3CR) of poly(methacrylated vanillin) (PMV)-sourced aldehydes was carried out with amines and phosphites. Overall, the surface KF-3CR on the cellulose fabric grafted with PMV represents a facile preparation of multifunctional molecules on cellulose surfaces along with α-amino phosphonate ester integrations.

AB - Compounds derived from two major biomass components, cellulose and lignin, were artificially recombined via the radiation-induced graft polymerization of vinyl monomers, which could be potentially sourced from lignin, onto cellulose fabric. This process yielded organic hybrids featuring a cellulose substrate and surface aldehyde groups from lignin-obtained vanillin. Then, the surface Kabachnik-Fields three-component reaction (KF-3CR) of poly(methacrylated vanillin) (PMV)-sourced aldehydes was carried out with amines and phosphites. Overall, the surface KF-3CR on the cellulose fabric grafted with PMV represents a facile preparation of multifunctional molecules on cellulose surfaces along with α-amino phosphonate ester integrations.

KW - Amino phosphonates

KW - Cellulose

KW - Lignin-sourced

KW - Multicomponent reactions

KW - Organic hybrids

UR - http://www.scopus.com/inward/record.url?scp=85062827523&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=85062827523&partnerID=8YFLogxK

U2 - 10.1021/acssuschemeng.8b06812

DO - 10.1021/acssuschemeng.8b06812

M3 - Article

AN - SCOPUS:85062827523

VL - 7

SP - 7795

EP - 7803

JO - ACS Sustainable Chemistry and Engineering

JF - ACS Sustainable Chemistry and Engineering

SN - 2168-0485

IS - 8

ER -