Novel concepts for organic syntheses based on interfaces and molecular machines

Shinsuke Ishihara, Yutaka Wakayama, Nobuya Hiroshiba, Jonathan P. Hill, Katsuhiko Ariga

研究成果: Article

3 引用 (Scopus)

抄録

Without doubt, organic chemistry has made significant contributions in improving the qualities of our lives. However, there exists a demand for well-designed molecules of complex structures with additional requirements for low-cost and low-energy production of the materials, which stimulate us to consider innovative concepts in organic synthetic methods. In order to propose innovative methods for next-generation organic synthetic procedures, we present two strategies, (i) organic synthesis within two-dimensional molecular patterns and (ii) organic synthesis driven by molecular machines working at interfaces. For example, synthesis of stereo-regulated polymeric materials in two-dimensional molecular arrays, tip-induced chemical reactions at a solid surface, sequential reactions guided by polymer chains, DNA-nanorobots on two-dimensional DNA origami, ester hydrolysis based on modified behavior of protonated amines at an interface, and several other methods are introduced as pioneering and innovative concepts.

元の言語English
ページ(範囲)428-438
ページ数11
ジャーナルCurrent Organic Synthesis
9
発行部数4
DOI
出版物ステータスPublished - 2012 8 9
外部発表Yes

Fingerprint

Synthetic Chemistry Techniques
Nanorobots
DNA
Organic Chemistry
Amines
Chemical reactions
Hydrolysis
Polymers
Esters
Molecules
Costs and Cost Analysis
Costs

ASJC Scopus subject areas

  • Organic Chemistry
  • Biochemistry

これを引用

Novel concepts for organic syntheses based on interfaces and molecular machines. / Ishihara, Shinsuke; Wakayama, Yutaka; Hiroshiba, Nobuya; Hill, Jonathan P.; Ariga, Katsuhiko.

:: Current Organic Synthesis, 巻 9, 番号 4, 09.08.2012, p. 428-438.

研究成果: Article

Ishihara, S, Wakayama, Y, Hiroshiba, N, Hill, JP & Ariga, K 2012, 'Novel concepts for organic syntheses based on interfaces and molecular machines', Current Organic Synthesis, 巻. 9, 番号 4, pp. 428-438. https://doi.org/10.2174/157017912802651384
Ishihara, Shinsuke ; Wakayama, Yutaka ; Hiroshiba, Nobuya ; Hill, Jonathan P. ; Ariga, Katsuhiko. / Novel concepts for organic syntheses based on interfaces and molecular machines. :: Current Organic Synthesis. 2012 ; 巻 9, 番号 4. pp. 428-438.
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