Nucleobase-Induced Supramolecular Polymerization in the Solid State

Stuart J. Rowan*, Phiriyatorn Suwanmala, Sona Sivakova

*この研究の対応する著者

研究成果: Article査読

62 被引用数 (Scopus)

抄録

Supramolecular polymerization, that is, the self-assembly of polymer-like materials through the utilization of the noncovalent bond, has been a developing area of research over the last decade. In this article, we report the synthesis of nucleobaseterminated (N6-anisoyl-adenine and thymine) low-molecular-weight poly(tetrahydrofuran) macromonomers (-1). The adenine-derived supramolecular telechelic polymer self-assembled in the solid state to yield materials with film- and fiber-forming capabilities. This material was thermally reversible and exhibited a ceiling temperature, above which a drop in viscosity was observed and fibers could no longer be obtained.

本文言語English
ページ(範囲)3589-3596
ページ数8
ジャーナルJournal of Polymer Science, Part A: Polymer Chemistry
41
22
DOI
出版ステータスPublished - 2003 11 15
外部発表はい

ASJC Scopus subject areas

  • ポリマーおよびプラスチック
  • 材料化学

フィンガープリント

「Nucleobase-Induced Supramolecular Polymerization in the Solid State」の研究トピックを掘り下げます。これらがまとまってユニークなフィンガープリントを構成します。

引用スタイル