Nucleophilic radical substitution of polychloroazines

Nobuhiro Kanomata, Mamoru Igarashi, Masaru Tada

研究成果: Article査読

4 被引用数 (Scopus)

抄録

Polychloroazines (1-6) are susceptible to homolytic chlorine substitution by alkyl radicals. In general, the chlorine at the ortho-position to the ring nitrogen is readily replaced by an alkyl radical like adamantyl and tert-butyl. However, the chlorine at the C2-position of pyrimidine did not show any sign of the radical substitution. The reactivity decreases in the order of adamantyl, tert-butyl, and isopropyl radicals.

本文言語English
ページ(範囲)1127-1138
ページ数12
ジャーナルHeterocycles
36
5
出版ステータスPublished - 1993 5 1

ASJC Scopus subject areas

  • Analytical Chemistry
  • Pharmacology
  • Organic Chemistry

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