On the reaction of (vinylimino)phosphoranes and related compounds synthesis and properties of novel 1,6-methanocyclodeca[b]cyclohepta[d]pyrrole

Makoto Nitta, Hiroyuki Kawaji, Nobuhiro Kanomata

研究成果: Article査読

18 被引用数 (Scopus)

抄録

The title compound was synthesized by thermal reaction of 3-phosphoranylidene-amino-1,6-methano[10]annulene with 2-chlorotropone in a single step. The examination of 1H NMR spectrum revealed that there is little contribution of peripheral 18-π electron conjugation, but it is rather composed of 1-azaazulene and methano[10]annulene moieties.

本文言語English
ページ(範囲)251-254
ページ数4
ジャーナルTetrahedron Letters
33
2
DOI
出版ステータスPublished - 1992

ASJC Scopus subject areas

  • Biochemistry
  • Drug Discovery
  • Organic Chemistry

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