On the reaction of (vinylimino)phosphoranes and related compounds synthesis and properties of novel 1,6-methanocyclodeca[b]cyclohepta[d]pyrrole

Makoto Nitta, Hiroyuki Kawaji, Nobuhiro Kanomata

    研究成果: Article

    18 引用 (Scopus)

    抄録

    The title compound was synthesized by thermal reaction of 3-phosphoranylidene-amino-1,6-methano[10]annulene with 2-chlorotropone in a single step. The examination of 1H NMR spectrum revealed that there is little contribution of peripheral 18-π electron conjugation, but it is rather composed of 1-azaazulene and methano[10]annulene moieties.

    元の言語English
    ページ（範囲）251-254
    ページ数4
    ジャーナルTetrahedron Letters
    巻33
    発行部数2
    DOI
    出版物ステータスPublished - 1992

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    Phosphoranes
    Pyrroles
    Hot Temperature
    Nuclear magnetic resonance
    Electrons
    Proton Magnetic Resonance Spectroscopy

    ASJC Scopus subject areas

    • Biochemistry
    • Organic Chemistry
    • Drug Discovery

    これを引用

    On the reaction of (vinylimino)phosphoranes and related compounds synthesis and properties of novel 1,6-methanocyclodeca[b]cyclohepta[d]pyrrole. / Nitta, Makoto; Kawaji, Hiroyuki; Kanomata, Nobuhiro.

    ：: Tetrahedron Letters, 巻 33, 番号 2, 1992, p. 251-254.

    研究成果: Article

    Nitta, M, Kawaji, H & Kanomata, N 1992, 'On the reaction of (vinylimino)phosphoranes and related compounds synthesis and properties of novel 1,6-methanocyclodeca[b]cyclohepta[d]pyrrole', Tetrahedron Letters, 巻. 33, 番号 2, pp. 251-254. https://doi.org/10.1016/0040-4039(92)88063-B
    Nitta M, Kawaji H, Kanomata N. On the reaction of (vinylimino)phosphoranes and related compounds synthesis and properties of novel 1,6-methanocyclodeca[b]cyclohepta[d]pyrrole. Tetrahedron Letters. 1992;33(2):251-254. https://doi.org/10.1016/0040-4039(92)88063-B
    Nitta, Makoto ; Kawaji, Hiroyuki ; Kanomata, Nobuhiro. / On the reaction of (vinylimino)phosphoranes and related compounds synthesis and properties of novel 1,6-methanocyclodeca[b]cyclohepta[d]pyrrole. ：: Tetrahedron Letters. 1992 ; 巻 33, 番号 2. pp. 251-254.
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    abstract = "The title compound was synthesized by thermal reaction of 3-phosphoranylidene-amino-1,6-methano[10]annulene with 2-chlorotropone in a single step. The examination of 1H NMR spectrum revealed that there is little contribution of peripheral 18-π electron conjugation, but it is rather composed of 1-azaazulene and methano[10]annulene moieties.",
    author = "Makoto Nitta and Hiroyuki Kawaji and Nobuhiro Kanomata",
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    doi = "10.1016/0040-4039(92)88063-B",
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    AU - Kanomata, Nobuhiro

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