On the reaction of (vinylimino)phosphoranes and related compounds synthesis and properties of novel 1,6-methanocyclodeca[b]cyclohepta[d]pyrrole

Makoto Nitta; Hiroyuki Kawaji; Nobuhiro Kanomata

doi:10.1016/0040-4039(92)88063-B

On the reaction of (vinylimino)phosphoranes and related compounds synthesis and properties of novel 1,6-methanocyclodeca[b]cyclohepta[d]pyrrole

Makoto Nitta, Hiroyuki Kawaji, Nobuhiro Kanomata

先進理工学部

研究成果: Article

18 引用（Scopus）

抜粋

The title compound was synthesized by thermal reaction of 3-phosphoranylidene-amino-1,6-methano[10]annulene with 2-chlorotropone in a single step. The examination of ¹H NMR spectrum revealed that there is little contribution of peripheral 18-π electron conjugation, but it is rather composed of 1-azaazulene and methano[10]annulene moieties.

元の言語	English
ページ（範囲）	251-254
ページ数	4
ジャーナル	Tetrahedron Letters
巻	33
発行部数	2
DOI	https://doi.org/10.1016/0040-4039(92)88063-B
出版物ステータス	Published - 1992

ASJC Scopus subject areas

Biochemistry
Drug Discovery
Organic Chemistry

文献にアクセス

10.1016/0040-4039(92)88063-B

フィンガープリント On the reaction of (vinylimino)phosphoranes and related compounds synthesis and properties of novel 1,6-methanocyclodeca[b]cyclohepta[d]pyrrole' の研究トピックを掘り下げます。これらはともに一意のフィンガープリントを構成します。

これを引用

Nitta, M., Kawaji, H., & Kanomata, N. (1992). On the reaction of (vinylimino)phosphoranes and related compounds synthesis and properties of novel 1,6-methanocyclodeca[b]cyclohepta[d]pyrrole. Tetrahedron Letters, 33(2), 251-254. https://doi.org/10.1016/0040-4039(92)88063-B

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abstract = "The title compound was synthesized by thermal reaction of 3-phosphoranylidene-amino-1,6-methano[10]annulene with 2-chlorotropone in a single step. The examination of 1H NMR spectrum revealed that there is little contribution of peripheral 18-π electron conjugation, but it is rather composed of 1-azaazulene and methano[10]annulene moieties.",

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