On the reaction of (vinylimino)phosphoranes and related compounds synthesis and properties of novel 1,6-methanocyclodeca[b]cyclohepta[d]pyrrole

Makoto Nitta, Hiroyuki Kawaji, Nobuhiro Kanomata

    研究成果: Article

    18 引用 (Scopus)

    抄録

    The title compound was synthesized by thermal reaction of 3-phosphoranylidene-amino-1,6-methano[10]annulene with 2-chlorotropone in a single step. The examination of 1H NMR spectrum revealed that there is little contribution of peripheral 18-π electron conjugation, but it is rather composed of 1-azaazulene and methano[10]annulene moieties.

    元の言語English
    ページ(範囲)251-254
    ページ数4
    ジャーナルTetrahedron Letters
    33
    発行部数2
    DOI
    出版物ステータスPublished - 1992

    Fingerprint

    Phosphoranes
    Pyrroles
    Hot Temperature
    Nuclear magnetic resonance
    Electrons
    Proton Magnetic Resonance Spectroscopy

    ASJC Scopus subject areas

    • Biochemistry
    • Organic Chemistry
    • Drug Discovery

    これを引用

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    abstract = "The title compound was synthesized by thermal reaction of 3-phosphoranylidene-amino-1,6-methano[10]annulene with 2-chlorotropone in a single step. The examination of 1H NMR spectrum revealed that there is little contribution of peripheral 18-π electron conjugation, but it is rather composed of 1-azaazulene and methano[10]annulene moieties.",
    author = "Makoto Nitta and Hiroyuki Kawaji and Nobuhiro Kanomata",
    year = "1992",
    doi = "10.1016/0040-4039(92)88063-B",
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    T1 - On the reaction of (vinylimino)phosphoranes and related compounds synthesis and properties of novel 1,6-methanocyclodeca[b]cyclohepta[d]pyrrole

    AU - Nitta, Makoto

    AU - Kawaji, Hiroyuki

    AU - Kanomata, Nobuhiro

    PY - 1992

    Y1 - 1992

    N2 - The title compound was synthesized by thermal reaction of 3-phosphoranylidene-amino-1,6-methano[10]annulene with 2-chlorotropone in a single step. The examination of 1H NMR spectrum revealed that there is little contribution of peripheral 18-π electron conjugation, but it is rather composed of 1-azaazulene and methano[10]annulene moieties.

    AB - The title compound was synthesized by thermal reaction of 3-phosphoranylidene-amino-1,6-methano[10]annulene with 2-chlorotropone in a single step. The examination of 1H NMR spectrum revealed that there is little contribution of peripheral 18-π electron conjugation, but it is rather composed of 1-azaazulene and methano[10]annulene moieties.

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    U2 - 10.1016/0040-4039(92)88063-B

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    JO - Tetrahedron Letters

    JF - Tetrahedron Letters

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